3D Interface-engineered Transition Metal Oxide/carbon Hybrid Structures for Efficient Bifunctional Oxygen Electrocatalysis in Alkaline and Acidic Environments - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook 3D Interface-engineered Transition Metal Oxide/carbon Hybrid Structures for Efficient Bifunctional Oxygen Electrocatalysis in Alkaline and Acidic Environments write by Simranjit Kaur Grewal. This book was released on 2021. 3D Interface-engineered Transition Metal Oxide/carbon Hybrid Structures for Efficient Bifunctional Oxygen Electrocatalysis in Alkaline and Acidic Environments available in PDF, EPUB and Kindle. Use of regenerative fuel cells requires efficient bifunctionality in oxygen electrocatalysis: oxygen reduction reaction (ORR) and oxygen evolution reaction (OER). Commonly used noble metals like Pt and its alloys (Pt/Ir or Pt/Ru) are often used for their catalytic activity, selectivity and stability in harsh environments. However, Pt can degrade during operation from catalyst agglomeration and poisoning. Therefore, researchers have used non-precious transition metal oxides (TMO) including Fe3O4, MnOx and Co3O4 and/or nanocarbon structures (NC) as potential catalyst. Composite structures where TMO nanoparticles are deposited onto a NC, derived from either graphene oxide (GO) or metal-organic frameworks (MOFs), have often been used. NCs have high surface area and excellent electronic conductivity, and while many studies assert these types of composite materials exhibiting synergistic effects in oxygen electrocatalysis, efforts to elucidate the origin of the synergy is lacking. This doctoral research explores how functional groups present on the surface of NCs affect synergy (reaction route and kinetics) of these electrocatalysis. To incur catalytically active sites between the metal oxides and carbon, the NCs basal plane were functionalized using acid treatments, after which various types of TMO/NC hybrids were synthesized using either wet process or vacuum deposition techniques. The hydroxylated CeO2/graphene hybrids showed the best ORR and OER performance in both alkaline and acidic media, in terms of onset/half-wave potential, electron transfer number, and current density when compared to the performance of benchmark catalysts: Pt/C (for ORR) and IrO2 (for OER). From a series of material and electrochemical analyses, it was determined that a strong tethering of TMOs on graphene's basal plane prohibited restacking and particle-carbon interfaces dictates the performance and reaction route, as indicated in density functional theory calculations. In addition, a hybrid catalyst of TiO2 nanodots, uniformly anchored on phosphorylated carbon by atomic layer deposition (ALD), showed even better ORR and OER performance in alkaline media when compared the aforementioned CeO2/graphene hybrid. Materials characterization emphasized a strong adhesion of TMOs on MOF structures; thus providing ample surface interactions for a favorable reaction route. Therefore, an activation of catalytic sites can be realized by proper engineering of interfaces in each hybrid system.
Frontiers in Materials: Rising Stars
Frontiers in Materials: Rising Stars - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Frontiers in Materials: Rising Stars write by Nicola Maria Pugno. This book was released on 2020-04-17. Frontiers in Materials: Rising Stars available in PDF, EPUB and Kindle. The Frontiers in Materials Editorial Office team are delighted to present the inaugural “Frontiers in Materials: Rising Stars” article collection, showcasing the high-quality work of internationally recognized researchers in the early stages of their independent careers. All Rising Star researchers featured within this collection were individually nominated by the Journal’s Chief Editors in recognition of their potential to influence the future directions in their respective fields. The work presented here highlights the diversity of research performed across the entire breadth of the materials science and engineering field, and presents advances in theory, experiment and methodology with applications to compelling problems. This Editorial features the corresponding author(s) of each paper published within this important collection, ordered by section alphabetically, highlighting them as the great researchers of the future. The Frontiers in Materials Editorial Office team would like to thank each researcher who contributed their work to this collection. We would also like to personally thank our Chief Editors for their exemplary leadership of this article collection; their strong support and passion for this important, community-driven collection has ensured its success and global impact. Laurent Mathey, PhD Journal Development Manager
Atomic and Nano Scale Materials for Advanced Energy Conversion, 2 Volumes
Atomic and Nano Scale Materials for Advanced Energy Conversion, 2 Volumes - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Atomic and Nano Scale Materials for Advanced Energy Conversion, 2 Volumes write by Zongyou Yin. This book was released on 2022-04-18. Atomic and Nano Scale Materials for Advanced Energy Conversion, 2 Volumes available in PDF, EPUB and Kindle. Atomic and Nano Scale Materials for Advanced Energy Conversion Discover the latest advancements in energy conversion technologies used to develop modern sustainable energy techniques In Atomic and Nano Scale Materials for Advanced Energy Conversion, expert interdisciplinary researcher Dr. Zongyou Yin delivers a comprehensive overview of nano-to-atomic scale materials science, the development of advanced electrochemical, photochemical, photoelectrochemical, and photovoltaic energy conversion strategies, and the applications for sustainable water splitting and other technologies. The book offers readers cutting-edge information of two-dimensional nano, mixed-dimensional nano, nano rare earth, clusters, and single atoms. It constructively evaluates emerging nano-to-atomic scale energy conversion technologies for academic research and development (R&D) researchers and industrial technique consultants and engineers. The author sets out a systematic analysis of recent energy-conversion science, covering topics like adaptable manufacturing of Van der Waals heterojunctions, mixed-dimensional junctions, tandem structures, and superlattices. He also discusses function-oriented engineering in polymorphic phases, photon absorption, excitons-charges conversion, non-noble plasmonics, and solid-liquid-gas interactions. Readers will also benefit from: A thorough introduction to emerging nanomaterials for energy conversion, including electrochemical, photochemical, photoelectrochemical, and photovoltaic energy conversion An exploration of clusters for energy conversion, including electrochemical, photochemical, and photoelectrochemical clusters Practical discussions of single atoms for energy conversion in electrochemical, photochemical, and photoelectrochemical energy conversion technologies A thorough analysis of future perspectives and directions in advanced energy conversion technology Perfect for materials scientists, photochemists, electrochemists, and inorganic chemists, Atomic and Nano Scale Materials for Advanced Energy Conversion is also a must-read resource for catalytic chemists interested in the intersection of advanced chemistry and physics in energy conversion technologies.
Defects in Two-Dimensional Materials
Defects in Two-Dimensional Materials - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Defects in Two-Dimensional Materials write by Rafik Addou. This book was released on 2022-02-14. Defects in Two-Dimensional Materials available in PDF, EPUB and Kindle. Defects in Two-Dimensional Materials addresses the fundamental physics and chemistry of defects in 2D materials and their effects on physical, electrical and optical properties. The book explores 2D materials such as graphene, hexagonal boron nitride (h-BN) and transition metal dichalcogenides (TMD). This knowledge will enable scientists and engineers to tune 2D materials properties to meet specific application requirements. The book reviews the techniques to characterize 2D material defects and compares the defects present in the various 2D materials (e.g. graphene, h-BN, TMDs, phosphorene, silicene, etc.). As two-dimensional materials research and development is a fast-growing field that could lead to many industrial applications, the primary objective of this book is to review, discuss and present opportunities in controlling defects in these materials to improve device performance in general or use the defects in a controlled way for novel applications. Presents the theory, physics and chemistry of 2D materials Catalogues defects of 2D materials and their impacts on materials properties and performance Reviews methods to characterize, control and engineer defects in 2D materials
Oxide Surfaces
Oxide Surfaces - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Oxide Surfaces write by . This book was released on 2001-05-21. Oxide Surfaces available in PDF, EPUB and Kindle. The book is a multi-author survey (in 15 chapters) of the current state of knowledge and recent developments in our understanding of oxide surfaces. The author list includes most of the acknowledged world experts in this field. The material covered includes fundamental theory and experimental studies of the geometrical, vibrational and electronic structure of such surfaces, but with a special emphasis on the chemical properties and associated reactivity. The main focus is on metal oxides but coverage extends from 'simple' rocksalt materials such as MgO through to complex transition metal oxides with different valencies.
