A Survey of Transition Metal Dinitrogen Complexes - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook A Survey of Transition Metal Dinitrogen Complexes write by Henry Adolph Onsgard. This book was released on 1971. A Survey of Transition Metal Dinitrogen Complexes available in PDF, EPUB and Kindle.
Transition Metal-Dinitrogen Complexes
Transition Metal-Dinitrogen Complexes - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Transition Metal-Dinitrogen Complexes write by Yoshiaki Nishibayashi. This book was released on 2019-01-25. Transition Metal-Dinitrogen Complexes available in PDF, EPUB and Kindle. A comprehensive book that explores nitrogen fixation by using transition metal-dinitrogen complexes Nitrogen fixation is one of the most prominent fields of research in chemistry. This book puts the focus on the development of catalytic ammonia formation from nitrogen gas under ambient reaction conditions that has been recently repowered by some research groups. With contributions from noted experts in the field, Transition Metal-Dinitrogen Complexes offers an important guide and comprehensive resource to the most recent research and developments on the topic of nitrogen fixation by using transition metal-dinitrogen. The book is filled with the information needed to understand the synthesis of transition metal-dinitrogen complexes and their reactivity. This important book: -Offers a resource for understanding nitrogen fixation chemistry that is essential for explosives, pharmaceuticals, dyes, and all forms of life -Includes the information needed for anyone interested in the field of nitrogen fixation by using transition metal-dinitrogen complexes -Contains state-of-the-art research on synthesis of transition metal-dinitrogen complexes and their reactivity in nitrogen fixation -Incorporates contributions from well-known specialists and experts with an editor who is an innovator in the field of dinitrogen chemistry Written for chemists and scientists with an interest in nitrogen fixation, Transition Metal-Dinitrogen Complexes is a must-have resource to the burgeoning field of nitrogen fixation by using transition metal-dinitrogen complexes.
Transition Metal Dinitrogen Complexes
Transition Metal Dinitrogen Complexes - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Transition Metal Dinitrogen Complexes write by . This book was released on 1973. Transition Metal Dinitrogen Complexes available in PDF, EPUB and Kindle. The central concern of this Thesis is the basic character of transition metal dinitrogen complexes towards Lewis acid moieties, with which they may give adducts containing the structural unit M-N-N-M' (M' is a Lewis acid moiety). This study was prompted by an interest in the problem of nitrogen fixation, since adduct formation is one of the few reactions of coordinated dinitrogen.Nitrogen fixation and certain aspects of base behaviour among transition metal complexes are reviewed in Chap. 1.The formation of adducts of dinitrogen and carbonyl complexes with AIR^ (R = Me, Ph and Cl) is described in Chap.2 and a base ranking of some of these complexes is drawn up from p.m.r. studies of equilibria involving the adducts (R = Me) and diethyl ether (Chap. 3 )* Adducts of trans -[ReCl(XY)(PMe2Ph)^] (l) (XY = N 2 ) with Mo- and W-(lv),-(V) and -(VI) acceptor moieties are described in Chap. Z*. The reactions of certain of the Re(l) dinitrogen complexes with the halogen acids HX are also discussed (Chap. 6).The bonding of N 2 and CO to transition metals is discussed (Chap. 7 )» with reference both to published physical measurements on their complexes, and to measurements of the dipole moments of the analogous complexes I (XY = N 2 and CO), described in Chap. 5.The preparation of some novel dinitrogen and carbonyl complexes is described in Chap. 8.
Computer Modelling of Transition-metal Dinitrogen Complexes
Computer Modelling of Transition-metal Dinitrogen Complexes - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Computer Modelling of Transition-metal Dinitrogen Complexes write by Sarah Anne Langford. This book was released on 1997. Computer Modelling of Transition-metal Dinitrogen Complexes available in PDF, EPUB and Kindle.
A Textbook of Inorganic Chemistry – Volume 1
A Textbook of Inorganic Chemistry – Volume 1 - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook A Textbook of Inorganic Chemistry – Volume 1 write by Mandeep Dalal. This book was released on 2017-01-01. A Textbook of Inorganic Chemistry – Volume 1 available in PDF, EPUB and Kindle. An advanced-level textbook of inorganic chemistry for the graduate (B.Sc) and postgraduate (M.Sc) students of Indian and foreign universities. This book is a part of four volume series, entitled "A Textbook of Inorganic Chemistry – Volume I, II, III, IV". CONTENTS: Chapter 1. Stereochemistry and Bonding in Main Group Compounds: VSEPR theory, dπ -pπ bonds, Bent rule and energetic of hybridization. Chapter 2. Metal-Ligand Equilibria in Solution: Stepwise and overall formation constants and their interactions, Trends in stepwise constants, Factors affecting stability of metal complexes with reference to the nature of metal ion and ligand, Chelate effect and its thermodynamic origin, Determination of binary formation constants by pH-metry and spectrophotometry. Chapter 3. Reaction Mechanism of Transition Metal Complexes – I: Inert and labile complexes, Mechanisms for ligand replacement reactions, Formation of complexes from aquo ions, Ligand displacement reactions in octahedral complexes- acid hydrolysis, Base hydrolysis, Racemization of tris chelate complexes, Electrophilic attack on ligands. Chapter 4. Reaction Mechanism of Transition Metal Complexes – II: Mechanism of ligand displacement reactions in square planar complexes, The trans effect, Theories of trans effect, Mechanism of electron transfer reactions – types; Outer sphere electron transfer mechanism and inner sphere electron transfer mechanism, Electron exchange. Chapter 5. Isopoly and Heteropoly Acids and Salts: Isopoly and Heteropoly acids and salts of Mo and W: structures of isopoly and heteropoly anions. Chapter 6. Crystal Structures: Structures of some binary and ternary compounds such as fluorite, antifluorite, rutile, antirutile, crystobalite, layer lattices- CdI2, BiI3; ReO3, Mn2O3, corundum, pervoskite, Ilmenite and Calcite. Chapter 7. Metal-Ligand Bonding: Limitation of crystal field theory, Molecular orbital theory, octahedral, tetrahedral or square planar complexes, π-bonding and molecular orbital theory. Chapter 8. Electronic Spectra of Transition Metal Complexes: Spectroscopic ground states, Correlation and spin-orbit coupling in free ions for Ist series of transition metals, Orgel and Tanabe-Sugano diagrams for transition metal complexes (d1 – d9 states), Calculation of Dq, B and β parameters, Effect of distortion on the d-orbital energy levels, Structural evidence from electronic spectrum, John-Tellar effect, Spectrochemical and nephalauxetic series, Charge transfer spectra, Electronic spectra of molecular addition compounds. Chapter 9. Magantic Properties of Transition Metal Complexes: Elementary theory of magneto - chemistry, Guoy’s method for determination of magnetic susceptibility, Calculation of magnetic moments, Magnetic properties of free ions, Orbital contribution, effect of ligand-field, Application of magneto-chemistry in structure determination, Magnetic exchange coupling and spin state cross over. Chapter 10. Metal Clusters: Structure and bonding in higher boranes, Wade’s rules, Carboranes, Metal Carbonyl Clusters - Low Nuclearity Carbonyl Clusters, Total Electron Count (TEC). Chapter 11. Metal-π Complexes: Metal carbonyls, structure and bonding, Vibrational spectra of metal carbonyls for bonding and structure elucidation, Important reactions of metal carbonyls; Preparation, bonding, structure and important reactions of transition metal nitrosyl, dinitrogen and dioxygen complexes; Tertiary phosphine as ligand.
