Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes write by A.E. Shilov. This book was released on 2006-04-11. Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes available in PDF, EPUB and Kindle. hemistry is the science about breaking and forming of bonds between atoms. One of the most important processes for organic chemistry is breaking bonds C–H, as well as C–C in various compounds, and primarily, in hydrocarbons. Among hydrocarbons, saturated hydrocarbons, alkanes (methane, ethane, propane, hexane etc. ), are especially attractive as substrates for chemical transformations. This is because, on the one hand, alkanes are the main constituents of oil and natural gas, and consequently are the principal feedstocks for chemical industry. On the other hand, these substances are known to be the less reactive organic compounds. Saturated hydrocarbons may be called the “noble gases of organic chemistry” and, if so, the first representative of their family – methane – may be compared with extremely inert helium. As in all comparisons, this parallel between noble gases and alkanes is not fully accurate. Indeed the transformations of alkanes, including methane, have been known for a long time. These reactions involve the interaction with molecular oxygen from air (burning – the main source of energy!), as well as some mutual interconversions of saturated and unsaturated hydrocarbons. However, all these transformations occur at elevated temperatures (higher than 300–500 °C) and are usually characterized by a lack of selectivity. The conversion of alkanes into carbon dioxide and water during burning is an extremely valuable process – but not from a chemist viewpoint.
Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes
Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes write by Aleksandr Evgenʹevich Shilov. This book was released on 2000. Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes available in PDF, EPUB and Kindle. Hemistry is the science about breaking and forming of bonds between atoms. One of the most important processes for organic chemistry is breaking bonds C-H, as well as C-C in various compounds, and primarily, in hydrocarbons. Among hydrocarbons, saturated hydrocarbons, alkanes (methane, ethane, propane, hexane etc.), are especially attractive as substrates for chemical transformations. This is because, on the one hand, alkanes are the main constituents of oil and natural gas, and consequently are the principal feedstocks for chemical industry. On the other hand, these substances are known to be the less reactive organic compounds. Saturated hydrocarbons may be called the "noble gases of organic chemistry" and, if so, the first representative of their family - methane - may be compared with extremely inert helium. As in all comparisons, this parallel between noble gases and alkanes is not fully accurate. Indeed the transformations of alkanes, including methane, have been known for a long time. These reactions involve the interaction with molecular oxygen from air (burning - the main source of energy!), as well as some mutual interconversions of saturated and unsaturated hydrocarbons. However, all these transformations occur at elevated temperatures (higher than 300-500 °C) and are usually characterized by a lack of selectivity. The conversion of alkanes into carbon dioxide and water during burning is an extremely valuable process - but not from a chemist viewpoint.
Activation of Saturated Hydrocarbons by Transition Metal Complexes
Activation of Saturated Hydrocarbons by Transition Metal Complexes - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Activation of Saturated Hydrocarbons by Transition Metal Complexes write by A.E. Shilov. This book was released on 1984-06-30. Activation of Saturated Hydrocarbons by Transition Metal Complexes available in PDF, EPUB and Kindle.
Catalytic Activation of Dioxygen by Metal Complexes
Catalytic Activation of Dioxygen by Metal Complexes - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Catalytic Activation of Dioxygen by Metal Complexes write by László I. Simándi. This book was released on 2012-12-06. Catalytic Activation of Dioxygen by Metal Complexes available in PDF, EPUB and Kindle. The activation of dioxygen by metal ions has both synthetic potential and biological relevance. Dioxygen is the cleanest oxidant for use in emission-free technologies to minimize pollution of the environment. The book gives a survey of those catalyst systems based on metal complexes which have been discovered and studied in the last decade. They activate molecular oxygen and effect the oxidation of various organic compounds under mild conditions. Much of the recent progress is due to a search for biomimetic catalysts that would duplicate the action of metalloenzymes. Mechanistic aspects are emphasized throughout the book. An introductonary chapter reviews the chemistry of transition metal dioxygen complexes, which are usually the active intermediates in the catalytic reactions discussed. Separate chapters are devoted to oxidation of saturated, unsaturated and aromatic hydrocarbons, phenols, catechols, oxo-compounds, phosphorus, sulfur and nitrogen compounds.
Hydrocarbon Chemistry, 2 Volume Set
Hydrocarbon Chemistry, 2 Volume Set - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Hydrocarbon Chemistry, 2 Volume Set write by George A. Olah. This book was released on 2017-10-02. Hydrocarbon Chemistry, 2 Volume Set available in PDF, EPUB and Kindle. This book provides an unparalleled contemporary assessment of hydrocarbon chemistry – presenting basic concepts, current research, and future applications. • Comprehensive and updated review and discussion of the field of hydrocarbon chemistry • Includes literature coverage since the publication of the previous edition • Expands or adds coverage of: carboxylation, sustainable hydrocarbons, extraterrestrial hydrocarbons • Addresses a topic of special relevance in contemporary science, since hydrocarbons play a role as a possible replacement for coal, petroleum oil, and natural gas as well as their environmentally safe use • Reviews of prior edition: “...literature coverage is comprehensive and ideal for quickly reviewing specific topics...of most value to industrial chemists...” (Angewandte Chemie) and “...useful for chemical engineers as well as engineers in the chemical and petrochemical industries.” (Petroleum Science and Technology)
