Alkane C-H Activation by Single-Site Metal Catalysis - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Alkane C-H Activation by Single-Site Metal Catalysis write by Pedro J. Pérez. This book was released on 2012-09-15. Alkane C-H Activation by Single-Site Metal Catalysis available in PDF, EPUB and Kindle. Over the past decade, much research effort has been devoted to the design and synthesis of new reagents and catalysts that can influence carbon-hydrogen bond activation, mainly because of the prospect that C−H activation could enable the conversion of cheap and abundant alkanes into valuable functionalized organic compounds. Alkane C-H Activation by Single-Site Metal Catalysis presents the current state-of-the-art development in the catalytic systems for the catalytic trans-formations of alkanes under homogeneous conditions. Chapter 1 offers a comprehensive summary of the main discoveries realized so far. Chapter 2 reviews the so-called electrophilic activation, initiated by Shulpín in the late 60s, and the base for the Catalytica system. Chapter 3 examines the catalytic borylation of alkanes, discovered by Hartwig, whereas chapter 4 provides an updated vision of the alkane dehydrogenation reaction. Chapter 5 covers the oxygenation of C-H bonds, a field of enormous interest with bioinorganic im-plications, and finally chapter 6 presents the functionalization of alkane C-H bonds by carbene or nitrene insertion. The history of C-H bond activation, and the current research described in this book, highlight the current research and present the reader with an outlook of this field which continues to be explored by an increasingly visionary and enthusiastic group of organic, organometallic, biological and physical chemists.
Catalytic Activation and Functionalisation of Light Alkanes
Catalytic Activation and Functionalisation of Light Alkanes - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Catalytic Activation and Functionalisation of Light Alkanes write by E.G. Derouane. This book was released on 2013-11-11. Catalytic Activation and Functionalisation of Light Alkanes available in PDF, EPUB and Kindle. Light alkanes tend to be resistant to many forms of activation. The horizontal approach of the present book covers homogeneous, heterogeneous and biological catalysis, thus allowing readers to gain an awareness of progress and ideas in research areas different from their own. The book contains both general chapters, giving an overview of the subject, and specialised contributions that deal with the details and state of the art. A specialist report is also included which gives a critical insight into current progress and discusses future prospects and major challenges. Audience: Newcomers and senior researchers in the field of alkane activation. The mixed theoretical and practical approach will be of interest to researchers and industrialists alike.
Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes
Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes write by A.E. Shilov. This book was released on 2006-04-11. Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes available in PDF, EPUB and Kindle. hemistry is the science about breaking and forming of bonds between atoms. One of the most important processes for organic chemistry is breaking bonds C–H, as well as C–C in various compounds, and primarily, in hydrocarbons. Among hydrocarbons, saturated hydrocarbons, alkanes (methane, ethane, propane, hexane etc. ), are especially attractive as substrates for chemical transformations. This is because, on the one hand, alkanes are the main constituents of oil and natural gas, and consequently are the principal feedstocks for chemical industry. On the other hand, these substances are known to be the less reactive organic compounds. Saturated hydrocarbons may be called the “noble gases of organic chemistry” and, if so, the first representative of their family – methane – may be compared with extremely inert helium. As in all comparisons, this parallel between noble gases and alkanes is not fully accurate. Indeed the transformations of alkanes, including methane, have been known for a long time. These reactions involve the interaction with molecular oxygen from air (burning – the main source of energy!), as well as some mutual interconversions of saturated and unsaturated hydrocarbons. However, all these transformations occur at elevated temperatures (higher than 300–500 °C) and are usually characterized by a lack of selectivity. The conversion of alkanes into carbon dioxide and water during burning is an extremely valuable process – but not from a chemist viewpoint.
Mechanistic Insights Into Alkane C-H Activation and Functionalization by Metal Oxide Surfaces and Organometallic Complexes
Mechanistic Insights Into Alkane C-H Activation and Functionalization by Metal Oxide Surfaces and Organometallic Complexes - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Mechanistic Insights Into Alkane C-H Activation and Functionalization by Metal Oxide Surfaces and Organometallic Complexes write by Mu-Jeng Cheng. This book was released on 2012. Mechanistic Insights Into Alkane C-H Activation and Functionalization by Metal Oxide Surfaces and Organometallic Complexes available in PDF, EPUB and Kindle.
Catalytic Transformations Via C-H Activation 1
Catalytic Transformations Via C-H Activation 1 - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Catalytic Transformations Via C-H Activation 1 write by Cheng Chien-Hong. This book was released on 2016. Catalytic Transformations Via C-H Activation 1 available in PDF, EPUB and Kindle. The reference work Science of Synthesis: Catalytic Transformations via C-H Activation covers the state of the art in C-H activation chemistry. Experts in the field present the best synthetic methods including typical or general experimental procedures. As such, this two volume set can serve as both a basis for the practical application of the techniques discussed, and as an educational resource to lay the foundations for future research. Volume 1 concerns the formation of C-C bonds by both arene and hetarene C-H activation. For the arenes the material is subdivided into arylation (using palladium(0), palladium(II)/palladium(IV), palladium(II), and ruthenium(II) catalysts), vinylation (using various palladium and ruthenium(III) catalysts), and alkylation (using various metal catalysts in combination with either functionalized alkanes or alkenes). For the hetarenes, the related coupling strategies are covered as a single topic using a variety of metal catalysts and coupling partners.
