Applications of EPR and NMR Spectroscopy in Homogeneous Catalysis

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Release : 2017-04-07
Genre : Science
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Book Rating : 645/5 ( reviews)

Applications of EPR and NMR Spectroscopy in Homogeneous Catalysis - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Applications of EPR and NMR Spectroscopy in Homogeneous Catalysis write by Evgenii Talsi. This book was released on 2017-04-07. Applications of EPR and NMR Spectroscopy in Homogeneous Catalysis available in PDF, EPUB and Kindle. This book reviews advances in important and practically relevant homogeneous catalytic transformations, such as single-site olefin polymerizations and chemo- and stereo-selective oxidations. Close attention is paid to the experimental investigation of the active sites of catalytic oxidation systems and their mechanisms. Major subjects include the applications of NMR and EPR spectroscopic techniques and data obtained by other physical methods. The book addresses a broad readership and focus on widespread techniques available in labs with NMR and EPR spectrometers.

Applications of EPR and NMR Spectroscopy in Homogeneous Catalysis

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Release : 2017
Genre : Catalysis
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Book Rating : 634/5 ( reviews)

Applications of EPR and NMR Spectroscopy in Homogeneous Catalysis - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Applications of EPR and NMR Spectroscopy in Homogeneous Catalysis write by Evgenii P. Talsi. This book was released on 2017. Applications of EPR and NMR Spectroscopy in Homogeneous Catalysis available in PDF, EPUB and Kindle. 4.2.1.2 Activation of L2iPrFeCl2 with AlMe3 -- 4.2.2 Bis(imino)pyridine Cobalt Ethylene Polymerization Catalysts -- 4.2.2.1 Activation of L2iPrCoIICl2 with MAO -- 4.2.2.2 Activation of L2iPrCoIICl2 with AlMe3 -- 4.2.3 a-Diimine Vanadium(III) Ethylene Polymerization Catalysts -- 4.2.3.1 System L2MeVCl3/AlMe3/[Ph3C][B(C6F5)4] -- 4.2.3.2 System L2MeVCl3/MAO -- 4.2.4 Ethylene Polymerization Precatalyst Based on Calix[4]arene Vanadium(V) Complex -- 4.2.4.1 Reaction of Calix[4]arene Vanadium(V) Complex with AlEt2Cl -- 4.2.4.2 Reaction of Calix[4]arene Vanadium(V) Complex with AlMe2Cl -- 4.2.4.3 Reaction of Calix[4]arene Vanadium(V) Complex with AlEt3 -- 4.2.5 Neutral NiII2-(N, O)-salicylaldiminato Olefin Polymerization Catalysts -- 4.2.5.1 Chain-Propagating Species Formed upon Ethylene Polymerization with Neutral Salicylaldiminato Nickel(II) Catalysts -- 4.2.5.2 Evaluation of the Size of Ni-Polymeryl Species by PFG NMR Spectroscopy -- 4.2.5.3 Catalyst Deactivation -- 4.2.6 Formation of Cationic Intermediates upon the Activation of Bis(imino)pyridine Nickel Catalysts -- 4.2.7 Cationic Intermediates Formed upon the Activation of Ni(II) Catalysts with AlMe2Cl and AlEt2Cl -- 4.3 On the Origin of Living Polymerization over o-Fluorinated Post-Titanocene Catalysts -- 4.4 Selective Ethylene Trimerization by Titanium Complex Bearing Phenoxy Imine Ligand -- References -- Index

Advances in Organometallic Chemistry

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Release : 2020-03-03
Genre : Science
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Book Rating : 918/5 ( reviews)

Advances in Organometallic Chemistry - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Advances in Organometallic Chemistry write by Pedro J. Perez. This book was released on 2020-03-03. Advances in Organometallic Chemistry available in PDF, EPUB and Kindle. Advances in Organometallic Chemistry, Volume 73, the latest release in this longstanding serial, is known for its comprehensive coverage of topics in organometallic synthesis, reactions, mechanisms, homogeneous catalysis, and more. It is ideal for a wide range of researchers involved in organometallic chemistry, including synthetic protocols, mechanistic studies and practical applications. Specific chapters in this new release include Metal carbonyl promoted multicomponent coupling of alkyne for synthesis of heterocyclic compounds, Group 10 metal(0) complexes stabilized by phosphorus and carbon donor ligands, Synthesis of Nitrogen-containing Molecules via Transition Metal-Catalyzed Reactions on Isoxazoles, Anthraniils and Benzoisoxazoles, and more. Contains contributions from leading authorities in the field of organometallic chemistry Covers topics in organometallic synthesis, reactions, mechanisms, homogeneous catalysis, and more Informs and updates readers on the latest developments in the field Carefully edited to provide easy-to-read material

Mechanisms in Homogeneous Catalysis

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Release : 2006-03-06
Genre : Science
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Book Rating : 871/5 ( reviews)

Mechanisms in Homogeneous Catalysis - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Mechanisms in Homogeneous Catalysis write by Brian Heaton. This book was released on 2006-03-06. Mechanisms in Homogeneous Catalysis available in PDF, EPUB and Kindle. While chemists using spectroscopic methods need to learn from the specialists, they do not normally read the spectroscopists' original papers. This book provides this very information -- summarizing some recent advances in the mechanistic understanding of metallocene polymerization catalysts and the role of NMR spectroscopy in these endeavors. Adopting a real practice-oriented approach, the authors focus on two of the most important spectroscopic techniques with two parts devoted to each of NMR and IR spectroscopy - as well as on important industrial applications with regard to the reaction discussed. Rather than providing a complete and exhaustive review of homogeneous hydrogenation and its detailed mechanisms, the book focuses on the specific spectroscopic techniques and the mechanistic information that has been obtained from their application. The result is unique in its scope, allowing chemists from different fields to learn which techniques can be applied for their specific synthetic problems. The prizewinning editor, Professor Brian Heaton, is the key player in the field, and has brought together here a team of authors to cater for specialists, and researchers in industry and academia.

Homogeneous Catalysis Concepts and Basics

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Release : 2024-08-30
Genre : Technology & Engineering
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Book Rating : 822/5 ( reviews)

Homogeneous Catalysis Concepts and Basics - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Homogeneous Catalysis Concepts and Basics write by Mohammad Reza Rahimpour. This book was released on 2024-08-30. Homogeneous Catalysis Concepts and Basics available in PDF, EPUB and Kindle. Homogeneous Hydrogenation and Metathesis Reactions, a volume in the Advances in Catalysis series, covers hydrogenation and metathesis reactions in two separate sections. The first section is devoted to homogeneous hydrogenation reactions and related processes, including hydrogenation of alkenes, esters, olefins, etc. In the second section, the metathesis reactions of olefins, alkenes, and alkynes are presented. In addition, the industrial application of homogeneous metathesis reactions is investigated. Includes thermodynamic and kinetic studies of homogeneous catalysts Describes transition metal, ligand and solvent role in homogeneous catalysts Explains preparation, characterization, deactivation and regeneration of homogeneous catalysts Presents homogeneous catalysts by clusters, carbenes, fixed metal-complexes, and liquid-liquid multiphase catalysts