Assembled Lanthanide Complexes with Advanced Photophysical Properties

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Release : 2018-04-07
Genre : Science
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Book Rating : 329/5 ( reviews)

Assembled Lanthanide Complexes with Advanced Photophysical Properties - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Assembled Lanthanide Complexes with Advanced Photophysical Properties write by Yuichi Hirai. This book was released on 2018-04-07. Assembled Lanthanide Complexes with Advanced Photophysical Properties available in PDF, EPUB and Kindle. This thesis provides essential information on the systematic design of assembled lanthanide complexes for functional luminescent materials. It discusses the relationships between assembled structures and photo, thermal, and mechanical properties on the basis of crystallography, spectroscopy, and thermodynamics. The described guidelines for assembled structures will be extremely valuable, both for industrial applications and for readers’ fundamental understanding of solid-state photophysics and materials chemistry. Luminescent lanthanide complexes are promising candidates for lighting devices, lasers, and bio-probes owing to their line-like and long-lived emission arising from characteristic 4f–4f transitions. Low-vibrational and asymmetrical coordination structures around lanthanide ions have been introduced to achieve strong luminescence, using specific organic ligands. Recently, assembled lanthanide complexes including coordination polymers and metal organic frameworks have increasingly attracted attention as a new class of luminescent materials offering thermal stability and color tunability. However, improving the luminescence efficiencies of these compounds remains a challenge, and specific molecular designs to control assembled structures and yield additional physical properties have not been established. The author provides a group of bent-angled bridging ligands to boost photoluminescence efficiency, and successfully introduces for the first time glass formability and strong triboluminescence properties.

Highly Luminescent Lanthanide Complexes with Specific Coordination Structures

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Release : 2014-04-08
Genre : Science
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Book Rating : 447/5 ( reviews)

Highly Luminescent Lanthanide Complexes with Specific Coordination Structures - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Highly Luminescent Lanthanide Complexes with Specific Coordination Structures write by Kohei Miyata. This book was released on 2014-04-08. Highly Luminescent Lanthanide Complexes with Specific Coordination Structures available in PDF, EPUB and Kindle. This thesis deals with strongly luminescent lanthanide complexes having novel coordination structures. Luminescent lanthanide complexes are promising candidates as active materials for EL devices, lasers, and bio-sensing applications. The organic ligands in lanthanide complexes control geometrical and vibrational frequency structures that are closely related to the luminescent properties. In most of the previous work, however, lanthanide complexes have high-vibrational frequency C–H units close to the metal center for radiationless transition. In this thesis, the luminescent properties of lanthanide complexes with low-vibrational frequency C–F and P=O units are elucidated in terms of geometrical, vibrational, and chemical structures. The author also describes lanthanide coordination polymers with both high thermal stability (decomposition point > 300°C) and strong-luminescent properties (emission quantum yield > 80%). The author believes that novel studies on the characteristic structures and photophysical properties of lanthanide complexes may open up a frontier field in photophysical, coordination and material chemistry.

Advanced Fluorescence Reporters in Chemistry and Biology II

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Release : 2010-09-08
Genre : Science
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Book Rating : 017/5 ( reviews)

Advanced Fluorescence Reporters in Chemistry and Biology II - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Advanced Fluorescence Reporters in Chemistry and Biology II write by Alexander P. Demchenko. This book was released on 2010-09-08. Advanced Fluorescence Reporters in Chemistry and Biology II available in PDF, EPUB and Kindle. With contributions by numerous experts

Synthesis, Structural Characterization and Photophysical Properties of Lanthanide Complexes Containing Polydentate Amide Ligands

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Release : 2001
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Synthesis, Structural Characterization and Photophysical Properties of Lanthanide Complexes Containing Polydentate Amide Ligands - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Synthesis, Structural Characterization and Photophysical Properties of Lanthanide Complexes Containing Polydentate Amide Ligands write by . This book was released on 2001. Synthesis, Structural Characterization and Photophysical Properties of Lanthanide Complexes Containing Polydentate Amide Ligands available in PDF, EPUB and Kindle.

Lanthanide Complexes of Phthalimide and Phthalamate Containing Ligands

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Release : 2012
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Lanthanide Complexes of Phthalimide and Phthalamate Containing Ligands - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Lanthanide Complexes of Phthalimide and Phthalamate Containing Ligands write by Gaoyum Chen. This book was released on 2012. Lanthanide Complexes of Phthalimide and Phthalamate Containing Ligands available in PDF, EPUB and Kindle.