Atmospheric Pressure Plasma Treatment of Polymers

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Release : 2013-06-19
Genre : Technology & Engineering
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Book Rating : 518/5 ( reviews)

Atmospheric Pressure Plasma Treatment of Polymers - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Atmospheric Pressure Plasma Treatment of Polymers write by Michael Thomas. This book was released on 2013-06-19. Atmospheric Pressure Plasma Treatment of Polymers available in PDF, EPUB and Kindle. An indispensable volume detailing the current and potential applications of atmospheric pressure plasma treatment by experts practicing in fields around the world Polymers are used in a wide variety of industries to fabricate legions of products because of their many desirable traits. However, polymers in general (and polyolefins, in particular) are innately not very adhesionable because of the absence of polar or reactive groups on their surfaces and concomitant low surface energy. Surface treatment of polymers, however, is essential to impart reactive chemical groups on their surfaces to enhance their adhesion characteristic. Proper surface treatment can endow polymers with improved adhesion without affecting the bulk properties. A plethora of techniques (ranging from wet to dry, simple to sophisticated, vacuum to non-vacuum) for polymer surface modification have been documented in the literature but the Atmospheric Pressure Plasma (APP) treatment has attracted much attention because it offers many advantages vis-a-vis other techniques, namely uniform treatment, continuous operation, no need for vacuum, simplicity, low cost, no environmental or disposal concern, and applicability to large area samples. Although the emphasis in this book is on the utility of APP treatment for enhancement of polymer adhesion, APP is also applicable and effective to modulate many other surface properties of polymers: superhydrophilicity, superhydrophobicity, anti-fouling, anti-fogging, anti-icing, cell adhesion, biocompatibility, tribological behavior, etc. The key features of Atmospheric Pressure Plasma Treatment of Polymers: Address design and functions of various types of reactors Bring out current and potential applications of APP treatment Represent the cumulative wisdom of many key academic and industry researchers actively engaged in this key and enabling technology

Atmospheric Pressure Plasma Treatment of Polymers

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Author :
Release : 2013-05-28
Genre : Technology & Engineering
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Book Rating : 218/5 ( reviews)

Atmospheric Pressure Plasma Treatment of Polymers - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Atmospheric Pressure Plasma Treatment of Polymers write by Michael Thomas. This book was released on 2013-05-28. Atmospheric Pressure Plasma Treatment of Polymers available in PDF, EPUB and Kindle. An indispensable volume detailing the current and potential applications of atmospheric pressure plasma treatment by experts practicing in fields around the world Polymers are used in a wide variety of industries to fabricate legions of products because of their many desirable traits. However, polymers in general (and polyolefins, in particular) are innately not very adhesionable because of the absence of polar or reactive groups on their surfaces and concomitant low surface energy. Surface treatment of polymers, however, is essential to impart reactive chemical groups on their surfaces to enhance their adhesion characteristic. Proper surface treatment can endow polymers with improved adhesion without affecting the bulk properties. A plethora of techniques (ranging from wet to dry, simple to sophisticated, vacuum to non-vacuum) for polymer surface modification have been documented in the literature but the Atmospheric Pressure Plasma (APP) treatment has attracted much attention because it offers many advantages vis-a-vis other techniques, namely uniform treatment, continuous operation, no need for vacuum, simplicity, low cost, no environmental or disposal concern, and applicability to large area samples. Although the emphasis in this book is on the utility of APP treatment for enhancement of polymer adhesion, APP is also applicable and effective to modulate many other surface properties of polymers: superhydrophilicity, superhydrophobicity, anti-fouling, anti-fogging, anti-icing, cell adhesion, biocompatibility, tribological behavior, etc. The key features of Atmospheric Pressure Plasma Treatment of Polymers: Address design and functions of various types of reactors Bring out current and potential applications of APP treatment Represent the cumulative wisdom of many key academic and industry researchers actively engaged in this key and enabling technology

Use of Atmospheric-Pressure Plasma Jet for Polymer Surface Modification

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Release : 2017
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Use of Atmospheric-Pressure Plasma Jet for Polymer Surface Modification - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Use of Atmospheric-Pressure Plasma Jet for Polymer Surface Modification write by . This book was released on 2017. Use of Atmospheric-Pressure Plasma Jet for Polymer Surface Modification available in PDF, EPUB and Kindle. Atmospheric-pressure plasma jets (APPJs) are playing an increasingly important role in materials processing procedures. Plasma treatment is a useful tool to modify surface properties of materials, especially polymers. Plasma reacts with polymer surfaces in numerous ways thus the type of process gas and plasma conditions must be explored for chosen substrates and materials to maximize desired properties. This report discusses plasma treatments and looks further into atmospheric-pressure plasma jets and the effects of gases and plasma conditions. Following the short literature review, a general overview of the future work and research at Los Alamos National Laboratory (LANL) is discussed.

Plasma Modification of Polyolefins

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Release : 2021-11-22
Genre : Technology & Engineering
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Book Rating : 644/5 ( reviews)

Plasma Modification of Polyolefins - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Plasma Modification of Polyolefins write by N. S. Baneesh. This book was released on 2021-11-22. Plasma Modification of Polyolefins available in PDF, EPUB and Kindle. This book addresses plasma modification of polyolefin surfaces. It comprises 21 chapters divided into three major sections. The first section covers the different techniques used for plasma modification of polyolefin surfaces and the effects of various gases as a surrounding medium, while the second provides a detailed analysis of the physics and chemistry of plasma modification and discusses various innovative characterization techniques, as well as ageing of the modified surface. It focuses on the analysis of changes in polymers’ surface chemistry using various spectroscopic techniques, and of changes in their surface morphology after plasma treatment using optical microscopy, electron microscopy and atomic force microscopy. In addition, it provides detailed information on the characterization of modified polymer surfaces. The book’s third and last section covers a range of applications of plasma-modified polyolefin surfaces varying from the packaging industry to the biomedical field, and shares valuable insights on the lifecycle analysis of plasma modification and modified surfaces.

Application of Atmospheric Pressure Plasma in Polymer and Composite Adhesion

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Release : 2016
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Application of Atmospheric Pressure Plasma in Polymer and Composite Adhesion - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Application of Atmospheric Pressure Plasma in Polymer and Composite Adhesion write by Hang Yu. This book was released on 2016. Application of Atmospheric Pressure Plasma in Polymer and Composite Adhesion available in PDF, EPUB and Kindle. An atmospheric pressure helium and oxygen plasma was used to investigate surface activation and bonding in polymer composites. This device was operated by passing 1.0-3.0 vol% of oxygen in helium through a pair of parallel plate metal electrodes powered by 13.56 or 27.12 MHz radio frequency power. The gases were partially ionized between the capacitors where plasma was generated. The reactive species in the plasma were carried downstream by the gas flow to treat the substrate surface. The temperature of the plasm gas reaching the surface of the substrate did not exceed 150 oC, which makes it suitable for polymer processing. The reactive species in the plasma downstream includes ~ 1016-1017 cm-3 atomic oxygen, ~ 1015 cm-3 ozone molecule, and ~ 1016 cm-3 metastable oxygen molecule (O21 g). The substrates were treated at 2-5 mm distance from the exit of the plasma. Surface properties of the substrates were characterized using water contact angle (WCA), atomic force microscopy (AFM), infrared spectroscopy (IR), and X-ray photoelectron spectroscopy (XPS). Subsequently, the plasma treated samples were bonded adhesively or fabricated into composites. The increase in mechanical strength was correlated to changes in the material composition and structure after plasma treatment. The work presented hereafter establishes atmospheric pressure plasma as an effective method to activate and to clean the surfaces of polymers and composites for bonding. This application can be further expanded to the activation of carbon fibers for better fiber-resin interactions during the fabrication of composites. Treating electronic grade FR-4 and polyimide with the He/O2 plasma for a few seconds changed the substrate surface from hydrophobic to hydrophilic, which allowed complete wetting of the surface by epoxy in underfill applications. Characterization of the surface by X-ray photoelectron spectroscopy shows formation of oxygenated functional groups, including hydroxyl, carbonyl, and carboxyl groups, on the polymer surface after plasma treatment. The resulting strength of the bond based on lap-shear and T-peel tests correlates well with the concentration of oxygen on the polymer surface. The failure modes observed for lap-shear and T-peel tests changed from interfacial to cohesive after the plasma activation. Treating carbon-fiber-reinforced epoxy composites with the atmospheric plasma resulted in the removal of fluorinated contaminants in shallow surface layers. For contaminants that diffused deeply into the composite surface, mechanical abrasion was needed in addition to the plasma treatment to remove the impurities. While cleaning the composite, plasma also generated active oxygen groups on the substrate surface. The presence of these groups improved the adhesive bonding strength of the composite even in the presence of residual fluorine contaminants. Thus, it was speculated that plasma treatment can promote better polymer adhesion with or without fluorine contamination. Carbon nanotube sheets were also treated by the helium oxygen plasma, and the CNT surface turn from super hydrophobic to hydrophilic after a few seconds of exposure. The nanotube surface contained 15 % of oxygen in the form of hydroxyl groups. Chemical coupling agents were added to the plasma activated CNT surfaces in order to crosslink the CNTs and to create bonding sites for the resin matrix. Stretched, activated and functionalized CNT was cured with dicyclopentadiene (DCPD) to produce a sheet composite with a tensile strength of 636 MPa, a modulus of 28 GPa, and a density of 1.4 g/cm3. This may be compared to aerospace-grade aluminum with tensile strength of 572 MPa, modulus of 72 GPa, and density of 2.7 g/cm3. This work demonstrates that new high-strength composite can be produced with the use of atmospheric plasma activation and chemical crosslinking of the fiber matrix.