Transition Metal Complexes of Neutral Eta1-Carbon Ligands

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Release : 2010-01-12
Genre : Science
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Book Rating : 211/5 ( reviews)

Transition Metal Complexes of Neutral Eta1-Carbon Ligands - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Transition Metal Complexes of Neutral Eta1-Carbon Ligands write by Remi Chauvin. This book was released on 2010-01-12. Transition Metal Complexes of Neutral Eta1-Carbon Ligands available in PDF, EPUB and Kindle. This book is part of a series that gives the broad scientific readership a comprehensive summary and critical overview of specific topics in the field of organometallic chemistry. This text focuses on transition metal complexes of neutral eta1-carbon ligands.

Reactions of Coordinated Ligands

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Release : 2012-12-06
Genre : Science
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Book Rating : 554/5 ( reviews)

Reactions of Coordinated Ligands - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Reactions of Coordinated Ligands write by P.S. Braterman. This book was released on 2012-12-06. Reactions of Coordinated Ligands available in PDF, EPUB and Kindle. This, the second and final volume of Reactions of Coordinated Ligands, describes the chemistry of ligands bound through non-carbon atoms, and of coordinated carbon dioxide. As before, emphasis is on the underlying mechanisms, which provide a unity of understanding for superficially disparate processes. The wide range of topics covered illustrates well both the versatility and the usefulness of coordination chemistry in the controlled activation of ligands. Looking to the future, carbon dioxide is the feedstock of last resort. The homogeneous reduction of dinitrogen to ammonia now seems unlikely to replace the Haber process, but solution reactions also lead to more complex, varied, and valuable products. Nitrogen monoxide, a "non innocent" ligand, impinges as pollutant and reagent. Its rich chemistry stems from its linked roles as three-electron donor, and as extremely powerful -acceptor. In the hydrolysis and condensation of complexed amides, esters etc. , metals act both as templates and as tunable and poly functional Lewis acids. Here the control of hydrophobic and steric interactions begins to model the subtle mechanisms of biological specificity. Finally, phosphorus and sulfur are imporant both as ligand atoms in themselves, and as anchors for other functionalities. I would like to thank all those who have been involved in the writing and production of this work, and also my colleagues old and new, at Glasgow and the University of North Texas, for their support. Paul S. Braterman v CONTENTS 1. Reactions of Coordinated Carbon Dioxide 1 J. D. Miller 1.

Carbon Ligands

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Release : 2021
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Book Rating : 492/5 ( reviews)

Carbon Ligands - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Carbon Ligands write by Yves Canac. This book was released on 2021. Carbon Ligands available in PDF, EPUB and Kindle. Homogeneous catalysis owes its success, in large part, to the development of a wide range of ligands with well-defined electronic and steric properties, which have thus made it possible to adjust the behavior of many organometallic complexes. However, ligands used in catalysis have long been centered on elements of group 15, and it is only more recently that carbon ligands have proved to be valuable alternatives with the emergence of cyclic diaminocarbenes (NHC).This Special Issue aims to provide a contemporary overview of the advances in carbon ligand chemistry from fundamental aspects to applications.

Transformation of Carbon Dioxide to Formic Acid and Methanol

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Release : 2017-10-26
Genre : Science
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Book Rating : 505/5 ( reviews)

Transformation of Carbon Dioxide to Formic Acid and Methanol - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Transformation of Carbon Dioxide to Formic Acid and Methanol write by Wan-Hui Wang. This book was released on 2017-10-26. Transformation of Carbon Dioxide to Formic Acid and Methanol available in PDF, EPUB and Kindle. This brief explains the principles and fundamentals of carbon dioxide utilization and highlights the transformation to fuels and value-added chemicals such as formic acid and methanol. It is divided into six chapters, including an introduction to the basics of CO2 utilization and transformation of CO2 to formic acid and methanol with homogeneous and heterogeneous catalysts, respectively. The brief will appeal to a wide readership of academic and industrial researchers focusing on homogeneous and heterogeneous catalysis, organometallic chemistry, green chemistry, energy conversion and storage.

Chiral Ligands

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Release : 2021-05-12
Genre : Medical
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Book Rating : 985/5 ( reviews)

Chiral Ligands - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Chiral Ligands write by Montserrat Diéguez. This book was released on 2021-05-12. Chiral Ligands available in PDF, EPUB and Kindle. Many new drugs on the market are chiral compounds, that is, they can exist in two non-superimposable mirror-image forms. Asymmetric catalysis encompasses a large variety of processes for obtaining such compounds. The performance of the catalyst in those processes largely depends on the ligand that makes up the catalyst. This book describes the most relevant ligand libraries for some key processes, including an overview of the state of art and the key mechanistic aspects that favor a high catalytic performance. Key Features: The book presents historical content from the time of discovery for each family of ligands. Provides a description of the synthetic route and the ligand library's application in various catalytic asymmetric reactions Suitable as supplementary reading for courses targeting the design, synthesis and application of chiral catalysts, asymmetric catalysis and sustainable production Edited by a distinguished scientist in the field, the book has a diverse audience including research groups in homogeneous catalysis, particularly asymmetric transformations