Computational Investigations Into the Structure and Reactivity of Small Transition Metal Clusters - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Computational Investigations Into the Structure and Reactivity of Small Transition Metal Clusters write by Matthew Addicoat. This book was released on 2009. Computational Investigations Into the Structure and Reactivity of Small Transition Metal Clusters available in PDF, EPUB and Kindle.
Ligated Transition Metal Clusters in Solid-state Chemistry
Ligated Transition Metal Clusters in Solid-state Chemistry - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Ligated Transition Metal Clusters in Solid-state Chemistry write by Jean-François Halet. This book was released on 2019-08-29. Ligated Transition Metal Clusters in Solid-state Chemistry available in PDF, EPUB and Kindle. This volume dedicated to the memory of Marcel Sergent who was a leader in this field for many years, addresses past achievements and recent developments in this vibrant area of research. Large classes of ligated transition metal clusters are produced either exclusively or most reliably by means of high-temperature solid-state reactions. Among them, the Chevrel-Sergent phases and related materials have generated enormous interest since their discovery in 1971. Today, these materials and their numerous derivatives still constitute a vivid area of research finding some applications not only in superconductivity, but also in catalysis, optics or thermoelectricity to mention a few.
Transition Metals in Coordination Environments
Transition Metals in Coordination Environments - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Transition Metals in Coordination Environments write by Ewa Broclawik. This book was released on 2019-03-16. Transition Metals in Coordination Environments available in PDF, EPUB and Kindle. This book focuses on the electronic properties of transition metals in coordination environments. These properties are responsible for the unique and intricate activity of transition metal sites in bio- and inorganic catalysis, but also pose challenges for both theoretical and experimental studies. Written by an international group of recognized experts, the book reviews recent advances in computational modeling and discusses their interplay using experiments. It covers a broad range of topics, including advanced computational methods for transition metal systems; spectroscopic, electrochemical and catalytic properties of transition metals in coordination environments; metalloenzymes and biomimetic compounds; and spin-related phenomena. As such, the book offers an invaluable resource for all researchers and postgraduate students interested in both fundamental and application-oriented research in the field of transition metal systems.
The Synergy Between Dynamics and Reactivity at Clusters and Surfaces
The Synergy Between Dynamics and Reactivity at Clusters and Surfaces - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook The Synergy Between Dynamics and Reactivity at Clusters and Surfaces write by L.J. Farrugia. This book was released on 2012-12-06. The Synergy Between Dynamics and Reactivity at Clusters and Surfaces available in PDF, EPUB and Kindle. The analogy between the chemistry of molecular transition metal clusters and the processes of chemisorption and catalysis at metal surfaces (the Cluster Surface analogy) has for a number of years provided an interplay between experimental and theoretical inorganic and physical chemists. This collaborative approach has born fruit in the use of well defined modes of metal-ligand bonding in discrete molecular clusters, models for metal-ligand binding on surfaces. Some of the key topics discussed in The Synergy between Dynamics and Reactivity at Clusters and Surfaces are: (1) Mechanisms of the fluxional behaviour in clusters in the liquid phase and the connections with diffusion processes on extended surfaces. The role of metal-metal bond breaking in diffusion. (2) Analogies in the structure of chemisorbed species and related ligands on metallic clusters. (3) Analogies between benzene surface chemistry on extended metal surfaces and on metal surfaces in molecular cluster compounds with particular reference to structural distortions. (4) The role of mobile precursors for dissociation of chemisorption on extended metals and on clusters. Are there analogies in the ligand attachment during cluster compound synthesis? (5) The role of defect sites on metal surfaces in catalyzing chemical reactions and the connection to the special bonding properties of sites on metal clusters having lowest metal-metal coordination. (6) The size of metal clusters needed to mimic surface phenomena on bulk metal surfaces. Different sites needed for different phenomena.
Atomically Precise Metal Clusters
Atomically Precise Metal Clusters - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Atomically Precise Metal Clusters write by Shuang-Quan Zang. This book was released on 2024-04-30. Atomically Precise Metal Clusters available in PDF, EPUB and Kindle. Atomically Precise Metal Clusters Thorough discussion on how surface modification and self-assembly play roles in the atomically precise formation and property tailoring of molecular clusters Atomically Precise Metal Clusters: Surface Engineering and Hierarchical Assembly summarizes and discusses the surface modification, assembly, and property tailoring of a wide variety of nanoclusters, including the well-explored metal clusters, addressing the structure–property relationships throughout. The atomic-level control in synthesis, new types of structures, and physical/chemical properties of nanoclusters are illustrated in various chapters. The controlled modification and assembly of metal nanoclusters is expected to have a major impact on future nanoscience research and other areas, with distinctive metal cluster-based function materials with precise structures uncovering exciting opportunities in both fundamental research and practical applications. Written by a highly qualified academic with significant research experience in the field, Atomically Precise Metal Clusters includes information on: Ligand engineering and assembly of coinage metal nanoclusters such as gold, silver, and copper Recent advances in post-modification of polyoxometalates and small transition metal chalcogenide superatom clusters Synthesis and assembly of cadmium chalcogenide supertetrahedral clusters and modification and assembly of Fe-S clusters Indium phosphide magic-sized clusters, ligand-tailoring platinum and palladium clusters, and metal oxo clusters (MOCs) Enabling access to desired functions in metal clusters for catalysis, optics, biomedicine, and other fields through surface engineering and supramolecular assembly A timely and comprehensive book that summarizes the recent progress in the surface modification and self-assembly of metal nanoclusters, Atomically Precise Metal Clusters provides essential guidance for graduate students and advanced researchers in material science, chemistry, biomedicine, and other disciplines.
