Fundamental and Technological Aspects of Organo-f-Element Chemistry

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Release : 2012-12-06
Genre : Science
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Book Rating : 069/5 ( reviews)

Fundamental and Technological Aspects of Organo-f-Element Chemistry - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Fundamental and Technological Aspects of Organo-f-Element Chemistry write by Tobin J. Marks. This book was released on 2012-12-06. Fundamental and Technological Aspects of Organo-f-Element Chemistry available in PDF, EPUB and Kindle. The past decade has seen a dramatic acceleration of activity and interest in phenomena surrounding lanthanide and actinide organo metallic compounds. Around the world, active research in organo-f element synthesis, chemistry, catalysis, crystallography, and quantum chemistry is in progress. This activity has spanned a remarkably wide range of disciplines, from synthetic/mechanistic inorganic and organic chemistry to radiochemistry, catalytic chemistry, spectroscopy (vibra tional, optical, magnetic resonance, photoelectron, Mossbauer), X-ray and neutron diffraction structural analysis, as well as to crystal field and molecular orbital theoretical studies at the interface of chemistry and physics. These investigations have been motivated both by fundamental and applied goals. The evidence that f-element organo metallic compounds have unique chemical and physical properties which cannot be duplicated by organometallic compounds of d-block elements has suggested many new areas of endeavor and application. For these reasons, a great many scientists felt the need for some international forum devoted exclusively to the subject of lanthanide and actinide organometallic compounds. In September of 1978, a NATO Advanced Study Institute entitled, "Organometallics of the f-Elements," was held at the SOGESTA Conference Center near Urbino, Italy. It was the universal feeling of the partic ipants that this first meeting was a great success and that vital international communication and collaboration had been stimulated. The principal lectures at this Institute were published by Reidel in 1979 as part of the NATO ASI Monograph Series ("Organometallics of the f-Elements," T. J. Marks and R. D. Fischer, editors).

Organoderivatives of Rare Earth Elements

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Release : 2012-12-06
Genre : Science
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Book Rating : 615/5 ( reviews)

Organoderivatives of Rare Earth Elements - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Organoderivatives of Rare Earth Elements write by M.N. Bochkarev. This book was released on 2012-12-06. Organoderivatives of Rare Earth Elements available in PDF, EPUB and Kindle. The present book is based on the work of M.N.Bochkarev, G.S.Kalinina, L.N. zakharov and S.Ya.Khorshev. The Russian edition of that book appeared under the same title in 1989 and covered literature data up to the middle of 1986. Since that time the number of publications on this subject increased significantly. In this volume we include all the data published up to the end of 1990, as well as some of the most important relevant articles of 1991. Therefore, this book should be considered as a new book, devoted to the same problems, rather than as just a translation of the mentioned issue. This book deals with compounds of scandium, yttrium, lanthanum and lanthanoids containing direct metal-carbon bond, Le. with the real organometallic complexes of these metals. Besides, the volume includes the rare earth complexes, in which organic ligand is bonded to the metal atom via the atom of another element of the Periodic Table. In other words, the book includes all classes of rare earth organoderivatives. Carboxilates, fl-diketonates and related chelates are the exceptions, because their properties are closer to inorganic compounds and they were fully described elsewhere. It should be noted, that "rare earth elements", "rare earth metals", "lanthanoids" and related terms are used in this book for indicating scandium, yttrium, lanthanum and the following 14 elements of the Periodic Table.

Modern Aspects of Rare Earths and their Complexes

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Release : 2003-12-09
Genre : Science
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Book Rating : 689/5 ( reviews)

Modern Aspects of Rare Earths and their Complexes - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Modern Aspects of Rare Earths and their Complexes write by Vinny R. Sastri. This book was released on 2003-12-09. Modern Aspects of Rare Earths and their Complexes available in PDF, EPUB and Kindle. In order to use rare earths successfully in various applications, a good understanding of the chemistry of these elements is of paramount importance. Nearly three to four decades have passed since titles such as The Rare Earths edited by F.H. Spedding and A.H. Daane, The chemistry of the Rare Earth Elements by N.E. Topp and Complexes of the Rare Earths by S.P. Sinha were published. There have been many international conferences and symposia on rare earths, as well as the series of volumes entitled Handbook of Physics and Chemistry of Rare Earths edited by K.A. Gschneidner and L. Eyring. Thus, there is a need for a new title covering modern aspects of rare earth complexes along with the applications. The present title consists of twelve chapters. 1. Introduction2. General aspects3. Stability of complexes4. Lanthanide complexes5. Structural chemistry of lanthanide compounds6. Organometallic complexes7. Kinetics and mechanisms of rare earths complexation8. Spectroscopy of lanthanide complexes9. Photoelectron spectroscopy of rare earths10. Lanthanide NMR shift reagents11. Environmental ecological biological aspects12. Applications The authors studied in schools headed by pioneers in rare earth chemistry, have a combined experience of one hundred and fifty years in inorganic chemistry, rare earth complex chemistry, nuclear and radiochemistry of rare earths and supramolecular chemistry. The present monograph is a product of this rich experience.

Synthetic Coordination and Organometallic Chemistry

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Release : 2003-04-25
Genre : Science
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Book Rating : 376/5 ( reviews)

Synthetic Coordination and Organometallic Chemistry - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Synthetic Coordination and Organometallic Chemistry write by Alexander D. Garnovskii. This book was released on 2003-04-25. Synthetic Coordination and Organometallic Chemistry available in PDF, EPUB and Kindle. This reference describes standard and nonstandard coordination modes of ligands in complexes, the intricacies of polyhedron-programmed and regioselective synthesis, and the controlled creation of coordination compounds such as molecular and hn-p-complexes, chelates, and homo- and hetero-nuclear compounds. It offers a clear and concise review of modern synthetic techniques of metal complexes as well as lesser known gas- and solid-phase synthesis, electrosynthesis, and microwave and ultrasonic treatment of the reaction system. The authors pay special attention to o-hydroxyazomethines and their S-, Se-containing analogues, b-diketones, and quinines, among others, and examine the immediate interaction of ligands and metal salts or carbonyls.

Advances in Organometallic Chemistry

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Release : 1994-04-22
Genre : Science
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Book Rating : 378/5 ( reviews)

Advances in Organometallic Chemistry - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Advances in Organometallic Chemistry write by . This book was released on 1994-04-22. Advances in Organometallic Chemistry available in PDF, EPUB and Kindle. This widely acclaimed serial contains authoritative reviews that address all aspects of organometallic chemistry, a field which has expanded enormously since the publication of Volume 1 in 1964. Almost all branchesof chemistry now interface with organometallic chemistry-the study of compounds containing carbon-metal bonds. Organometallic compounds range from species that are so reactive that they only have a transient existence at ambient temperatures to those thatare thermally very stable. They are used extensively in the synthesis of useful compounds on both small and large scales. Industrial processes involving plastics, polymers, electronic materials, and pharmaceuticals all depend on advances in organometallic chemistry. In basic research, organometallics have contributed inter alia to: Metal cluster chemistry Surface chemistry The stabilization of highly reactive species by metal coordination Chiral synthesis The formulation of multiple bonds between carbon and the other elements and between the elements themselves Each volume of Advances in Organometallic Chemistry contains an index, and each chapter includes references