Guide to Fluorine NMR for Organic Chemists

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Release : 2009-05-20
Genre : Science
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Book Rating : 393/5 ( reviews)

Guide to Fluorine NMR for Organic Chemists - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Guide to Fluorine NMR for Organic Chemists write by W. R. Dolbier. This book was released on 2009-05-20. Guide to Fluorine NMR for Organic Chemists available in PDF, EPUB and Kindle. AN UNPARALLELED ONE-STOP GUIDE TO FLUORINE NMR Guide to Fluorine NMR for Organic Chemists provides a unique single source on both fluorine NMR and the impact of fluorine substituents on proton and carbon NMR spectra. Helping working chemists overcome the challenges associated with the synthetic methodologies of fluorinated compounds, this guide enables the effective use of these increasingly popular spectroscopic techniques to accurately characterize compounds that contain fluorine. Following a thorough introduction of fluorinated compounds, chapters in the text cover: An overview of fluorine NMR The single fluorine substituent The CF2 group The trifluoromethyl group More heavily fluorinated compounds Compounds and substituents with fluorine directly bound to heteroatoms With unparalleled depth and completeness, the coverage ranges from those compounds containing only a few fluorinated substituents, typically employed in pharmaceutical and agricultural applications, to more heavily fluorinated compounds. Featuring NMR data for more than 1,000 specific compunds and including more than 100 exemplary spectra, Guide to Fluorine NMR for Organic Chemists gives the working chemist and advanced student an essential tool for understanding cutting-edge NMR techniques and interpreting the resulting spectroscopic data.

Guide to Fluorine NMR for Organic Chemists

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Release : 2016-08-22
Genre : Science
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Book Rating : 11X/5 ( reviews)

Guide to Fluorine NMR for Organic Chemists - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Guide to Fluorine NMR for Organic Chemists write by William R. Dolbier, Jr.. This book was released on 2016-08-22. Guide to Fluorine NMR for Organic Chemists available in PDF, EPUB and Kindle. Following its well-received predecessor, this book offers an essential guide to chemists for understanding fluorine in spectroscopy. With over 1000 compounds and 100 spectra, the second edition adds new data – featuring fluorine effects on nitrogen NMR, chemical shifts, and coupling constants. • Explains how to successfully incorporate fluorine into target molecules and utilize fluorine substituents to structurally characterize organic compounds • Includes new data on nitrogen NMR, focusing on N-15, to portray the influence of fluorine upon nitrogen NMR chemical shifts and coupling constants • Expands on each chapter from the first edition with additional data and updated discussion from recent findings • "The flawless ordering of material covered in this stand-alone volume is such that information can be found very easily." – Angewandte Chemie review of the first edition, 2010

Guide to Fluorine NMR for Organic Chemists

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Release : 2016-08-24
Genre : Science
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Book Rating : 098/5 ( reviews)

Guide to Fluorine NMR for Organic Chemists - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Guide to Fluorine NMR for Organic Chemists write by William R. Dolbier, Jr.. This book was released on 2016-08-24. Guide to Fluorine NMR for Organic Chemists available in PDF, EPUB and Kindle. Following its well-received predecessor, this book offers an essential guide to chemists for understanding fluorine in spectroscopy. With over 1000 compounds and 100 spectra, the second edition adds new data – featuring fluorine effects on nitrogen NMR, chemical shifts, and coupling constants. • Explains how to successfully incorporate fluorine into target molecules and utilize fluorine substituents to structurally characterize organic compounds • Includes new data on nitrogen NMR, focusing on N-15, to portray the influence of fluorine upon nitrogen NMR chemical shifts and coupling constants • Expands on each chapter from the first edition with additional data and updated discussion from recent findings • "The flawless ordering of material covered in this stand-alone volume is such that information can be found very easily." – Angewandte Chemie review of the first edition, 2010

Essential Practical NMR for Organic Chemistry

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Release : 2010-12-07
Genre : Science
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Book Rating : 221/5 ( reviews)

Essential Practical NMR for Organic Chemistry - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Essential Practical NMR for Organic Chemistry write by S. A. Richards. This book was released on 2010-12-07. Essential Practical NMR for Organic Chemistry available in PDF, EPUB and Kindle. This book describes the use of NMR spectroscopy for dealing with problems of small organic molecule structural elucidation. It features a significant amount of vital chemical shift and coupling information but more importantly, it presents sound principles for the selection of the techniques relevant to the solving of particular types of problem, whilst stressing the importance of extracting the maximum available information from the simple 1-D proton experiment and of using this to plan subsequent experiments. Proton NMR is covered in detail, with a description of the fundamentals of the technique, the instrumentation and the data that it provides before going on to discuss optimal solvent selection and sample preparation. This is followed by a detailed study of each of the important classes of protons, breaking the spectrum up into regions (exchangeables, aromatics, heterocyclics, alkenes etc.). This is followed by consideration of the phenomena that we know can leave chemists struggling; chiral centres, restricted rotation, anisotropy, accidental equivalence, non-first-order spectra etc. Having explained the potential pitfalls that await the unwary, the book then goes on to devote chapters to the chemical techniques and the most useful instrumental ones that can be employed to combat them. A discussion is then presented on carbon-13 NMR, detailing its pros and cons and showing how it can be used in conjunction with proton NMR via the pivotal 2-D techniques (HSQC and HMBC) to yield vital structural information. Some of the more specialist techniques available are then discussed, i.e. flow NMR, solvent suppression, Magic Angle Spinning, etc. Other important nuclei are then discussed and useful data supplied. This is followed by a discussion of the neglected use of NMR as a tool for quantification and new techniques for this explained. The book then considers the safety aspects of NMR spectroscopy, reviewing NMR software for spectral prediction and data handling and concludes with a set of worked Q&As.

NMR in Organometallic Chemistry

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Release : 2013-07-26
Genre : Science
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Book Rating : 292/5 ( reviews)

NMR in Organometallic Chemistry - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook NMR in Organometallic Chemistry write by Paul S. Pregosin. This book was released on 2013-07-26. NMR in Organometallic Chemistry available in PDF, EPUB and Kindle. The first and ultimate guide for anyone working in transition organometallic chemistry and related fields, providing the background and practical guidance on how to efficiently work with routine research problems in NMR. The book adopts a problem-solving approach with many examples taken from recent literature to show readers how to interpret the data. Perfect for PhD students, postdocs and other newcomers in organometallic and inorganic chemistry, as well as for organic chemists involved in transition metal catalysis.