Heteronuclear Metal-Metal Bonds - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Heteronuclear Metal-Metal Bonds write by R.D. Adams. This book was released on 2004-09-16. Heteronuclear Metal-Metal Bonds available in PDF, EPUB and Kindle. The number of organometallic compounds containing heteronuclear metal-metal bonds has grown tremendously in the last ten years. Also known as cluster compounds, these compounds have been found to exhibit a rich diversity of molecular structures and reactivities. Descriptions of the structures and transformations of the complexes are central features. Separate chapters have been prepared for compounds containing bonds between transition metals and the metals of the copper and zinc subgroups. Unlike COMC, this volume contains an entire chapter devoted to studies of heteronuclear metal compounds in catalysis.
Comprehensive Organometallic Chemistry II: Heteronuclear metal-metal bonds
Comprehensive Organometallic Chemistry II: Heteronuclear metal-metal bonds - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Comprehensive Organometallic Chemistry II: Heteronuclear metal-metal bonds write by . This book was released on 1995. Comprehensive Organometallic Chemistry II: Heteronuclear metal-metal bonds available in PDF, EPUB and Kindle.
Compounds Containing Heteronuclear Metal-metal Bonds
Compounds Containing Heteronuclear Metal-metal Bonds - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Compounds Containing Heteronuclear Metal-metal Bonds write by F. Gordon. This book was released on 1986. Compounds Containing Heteronuclear Metal-metal Bonds available in PDF, EPUB and Kindle.
Compounds Containing Heteronuclear Metal-Metal Bonds
Compounds Containing Heteronuclear Metal-Metal Bonds - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Compounds Containing Heteronuclear Metal-Metal Bonds write by F. G. Stone. This book was released on 1986. Compounds Containing Heteronuclear Metal-Metal Bonds available in PDF, EPUB and Kindle. This Report describes the synthesis and structural characterisation of several gold-ruthenium cluster compounds, as well as the discovery of the first trimetallic complexes containing the hexanuclear core structures MM'Ru4 (M = Ag, M' = Cu; M = Au, M' =Cu; M = Au, M' = Ag). Using variable temperature 31P-1H nuclear magnetic resonance spectroscopy we have observed polytopal rearrangements of these clusters in solution. Also described are new heteronuclear cluster compounds containing bonds between iridium and osmium or platinum. In a further study the first mixed-metal clusters involving osmium and platinum with interstitial carbido ligands are reported. Rational synthetic routes have been developed for preparing cluster compounds containing chains and rings of metal atoms in which the metal-metal bonds are bridged by alkylidyne groups. This work has led to the characterisation, via X-ray diffraction and n.m.r. studies, of novel compounds with core structures having eight metal atoms (Pt4W4 or Ni2Pt2W4) in a ring in the shape of a 'star'.
Transition Metal Carbonyl Cluster Chemistry
Transition Metal Carbonyl Cluster Chemistry - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Transition Metal Carbonyl Cluster Chemistry write by Paul J. Dyson. This book was released on 2018-10-03. Transition Metal Carbonyl Cluster Chemistry available in PDF, EPUB and Kindle. Transition metal carbonyl clusters (TMCCs) continue to inspire great interest in chemical research, as much for their fascinating structures as for potential industrial applications conferred by their unique properties. This highly accessible book introduces the bonding, structure, spectroscopic properties, and characterization of clusters, and then explores their synthesis, reactivity, reaction mechanisms and use in organic synthesis and catalysis. Transition Metal Carbonyl Cluster Chemistry describes models and rules that correlate cluster structure with electron count, which are then applied in worked examples. Subsequent chapters explain how bonding relates to molecular structure, demonstrate the use of spectroscopic techniques such as NMR, IR and MS in cluster chemistry, and outline the factors contributing to the stability, dynamics and reactivity of clusters. The second part of this book discusses the synthesis and applications of TMCCs. It emphasizes the differences between the reactivities of clusters vs. mononuclear metal complexes, contingent to the availability of multiple-bonding sites and heterosite reactivity. The final chapters discuss reactions in which clusters act as homogeneous catalysts; including discussion on the use of solid and biphasic liquid-liquid supported clusters in heterogeneous catalysts. A useful reference for those commencing further research or post-graduate study on metal carbonyl clusters and advanced organometallic chemistry, this book is also a cornerstone addition to academic and libraries as well as private collections.
