Luminescent 1-hydroxy-2-pyridinone Chelates of Lanthanides

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Release : 2017
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Luminescent 1-hydroxy-2-pyridinone Chelates of Lanthanides - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Luminescent 1-hydroxy-2-pyridinone Chelates of Lanthanides write by . This book was released on 2017. Luminescent 1-hydroxy-2-pyridinone Chelates of Lanthanides available in PDF, EPUB and Kindle. The present invention provides luminescent complexes between a lanthanide ion and an organic ligand which contains 1,2-hydroxypyridinone units. The complexes of the invention are stable in aqueous solutions and are useful as molecular probes, for example in medical diagnostics and bioanalytical assay systems. The invention also provides methods of using the complexes of the invention.

Highly Luminescent Lanthanide Complexes of 1 Hydroxy-2-pyridinones

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Release : 2007
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Highly Luminescent Lanthanide Complexes of 1 Hydroxy-2-pyridinones - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Highly Luminescent Lanthanide Complexes of 1 Hydroxy-2-pyridinones write by . This book was released on 2007. Highly Luminescent Lanthanide Complexes of 1 Hydroxy-2-pyridinones available in PDF, EPUB and Kindle. The synthesis, X-ray structure, stability, and photophysical properties of several trivalent lanthanide complexes formed from two differing bis-bidentate ligands incorporating either alkyl or alkyl ether linkages and featuring the 1-hydroxy-2-pyridinone (1,2-HOPO) chelate group in complex with Eu(III), Sm(III) and Gd(III) are reported. The Eu(III) complexes are among some of the best examples, pairing highly efficient emission ([Phi]{sub tot}{sup Eu} ≈ 21.5%) with high stability (pEu ≈ 18.6) in aqueous solution, and are excellent candidates for use in biological assays. A comparison of the observed behavior of the complexes with differing backbone linkages shows remarkable similarities, both in stability and photophysical properties. Low temperature photophysical measurements for a Gd(III) complex were also used to gain insight into the electronic structure, and were found to agree with corresponding TD-DFT calculations for a model complex. A comparison of the high resolution Eu(III) emission spectra in solution and from single crystals also revealed a more symmetric coordination geometry about the metal ion in solution due to dynamic rotation of the observed solid state structure.

Lanthanide Luminescence

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Release : 2011-06-21
Genre : Science
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Book Rating : 236/5 ( reviews)

Lanthanide Luminescence - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Lanthanide Luminescence write by Pekka Hänninen. This book was released on 2011-06-21. Lanthanide Luminescence available in PDF, EPUB and Kindle. Lanthanides have fascinated scientists for more than two centuries now, and since efficient separation techniques were established roughly 50 years ago, they have increasingly found their way into industrial exploitation and our everyday lives. Numerous applications are based on their unique luminescent properties, which are highlighted in this volume. It presents established knowledge about the photophysical basics, relevant lanthanide probes or materials, and describes instrumentation-related aspects including chemical and physical sensors. The uses of lanthanides in bioanalysis and medicine are outlined, such as assays for in vitro diagnostics and research. All chapters were compiled by renowned scientists with a broad audience in mind, providing both beginners in the field and advanced researchers with comprehensive information on on the given subject.

USPTO Image File Wrapper Petition Decisions 0439

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USPTO Image File Wrapper Petition Decisions 0439 - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook USPTO Image File Wrapper Petition Decisions 0439 write by . This book was released on . USPTO Image File Wrapper Petition Decisions 0439 available in PDF, EPUB and Kindle.

Advances in Inorganic Chemistry

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Release : 2008-10-06
Genre : Science
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Book Rating : 56X/5 ( reviews)

Advances in Inorganic Chemistry - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Advances in Inorganic Chemistry write by Rudi van Eldik. This book was released on 2008-10-06. Advances in Inorganic Chemistry available in PDF, EPUB and Kindle. The Advances in Inorganic Chemistry series present timely and informative summaries of the current progress in a variety of subject areas within inorganic chemistry, ranging from bio-inorganic to solid state studies. This acclaimed serial features reviews written by experts in the field and serves as an indispensable reference to advanced researchers. Each volume contains an index, and each chapter is fully referenced. Features comprehensive reviews on the latest developments Includes contributions from leading experts in the field Serves as an indispensable reference to advanced researchers