Main Group and Transition Metal Complexes Supported by Carbon, Sulfur, and Selenium Donor Ligands

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Release : 2018
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Main Group and Transition Metal Complexes Supported by Carbon, Sulfur, and Selenium Donor Ligands - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Main Group and Transition Metal Complexes Supported by Carbon, Sulfur, and Selenium Donor Ligands write by Patrick Quinlivan. This book was released on 2018. Main Group and Transition Metal Complexes Supported by Carbon, Sulfur, and Selenium Donor Ligands available in PDF, EPUB and Kindle. For example, a mixture of [TmBut]ZnMe and Me2Cd form an equilibrium mixture with [TmBut]CdMe and Me2Zn. Furthermore, transfer of the [TmBut] ligand between the metal centers is possible too. This is demonstrated by the transfer of [TmBut] from mercury to zinc in the methyl system, [TmBut]HgMe/Me2Zn. Additionally, transfer of [TmBut] from zinc to mercury is also observed upon treatment of [TmBut]2Zn with HgI2 to afford [TmBut]HgI and [TmBut]ZnI, thereby indicating that the nature of the co-ligand has a profound effect on the thermodynamics of ligand exchange. Chapter 3 explores the coordination chemistry of the selenium donor ligand, H(sebenzimMe). H(sebenzimMe) is able to coordinate metal centers through the selenium atom in a dative fashion, and, depending upon the metal center, up to four H(sebenzimMe) ligands can coordinate the same metal. Additionally, H(sebenzimMe) can be deprotonated to form [sebenzimMe]–, allowing for the potential of an LX coordination mode, which results in bridging complexes for the metal compounds investigated.

Main Group and Transition Metal Complexes Supported by Multidentate Tripodal Ligands that Feature Nitrogen, Oxygen and Sulfur Donors

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Release : 2013
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Main Group and Transition Metal Complexes Supported by Multidentate Tripodal Ligands that Feature Nitrogen, Oxygen and Sulfur Donors - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Main Group and Transition Metal Complexes Supported by Multidentate Tripodal Ligands that Feature Nitrogen, Oxygen and Sulfur Donors write by . This book was released on 2013. Main Group and Transition Metal Complexes Supported by Multidentate Tripodal Ligands that Feature Nitrogen, Oxygen and Sulfur Donors available in PDF, EPUB and Kindle. Chapter 5 describes two multidentate, L3X type ligands, which feature [CN3] and [CNO2] donors, namely tris(2 pyridylseleno)methane, [Tpsem]H, and bis(2-pyridonyl)(pyridin-2-yloxy)methane, [O-poBpom]H. They have been synthesized, characterized, and employed in the synthesis of zinc and cadmium complexes. Chapter 6 describes the synthesis and structural characterization of a new [Tp] ligand featuring an allyl substituent on the central boron atom, namely [allylTpBut]Li is reported. The compound reacts steadily with CH3CH2SH under 350 nm UV light via a thiol-ene click reaction. The resulting [CH3CH2S(CH2)3TpBut]Li complex can further react with metal halide. For example, the reaction of [CH3CH2S(CH2)3TpBut]Li with ZnI2 produced [CH3CH2S(CH2)3TpBut]ZnI at room temperature. This study provides a simple model on the immobilization of [Tp] metal complexes to the polymer chains with -SH terminals.

Metal Complexes with Sulfur and Selenium Donor Ligands

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Metal Complexes with Sulfur and Selenium Donor Ligands - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Metal Complexes with Sulfur and Selenium Donor Ligands write by . This book was released on . Metal Complexes with Sulfur and Selenium Donor Ligands available in PDF, EPUB and Kindle. HKUST Call Number: Thesis CHEM 2009 Chiu.

Transition Metals and Sulfur – A Strong Relationship for Life

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Release : 2020-04-06
Genre : Science
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Book Rating : 943/5 ( reviews)

Transition Metals and Sulfur – A Strong Relationship for Life - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Transition Metals and Sulfur – A Strong Relationship for Life write by Martha Sosa Torres. This book was released on 2020-04-06. Transition Metals and Sulfur – A Strong Relationship for Life available in PDF, EPUB and Kindle. Metal Ions in Life Sciences links coordination chemistry and biochemistry in their widest sense and thus increases our understanding of the relationship between the chemistry of metals and life processes; in fact, it is an old wisdom that metals are indispensable for life. The series reflects the interdisciplinary nature of Biological Inorganic Chemistry and coordinates the efforts of scientists in numerous interconnecting research fields.

The Stability of Transition-metal Complexes with Ligands Containing Arsenic, Sulphur and Selenium as Donor Atoms

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Release : 1968
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The Stability of Transition-metal Complexes with Ligands Containing Arsenic, Sulphur and Selenium as Donor Atoms - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook The Stability of Transition-metal Complexes with Ligands Containing Arsenic, Sulphur and Selenium as Donor Atoms write by Colin Sherrington. This book was released on 1968. The Stability of Transition-metal Complexes with Ligands Containing Arsenic, Sulphur and Selenium as Donor Atoms available in PDF, EPUB and Kindle.