Metal Catalysts in Olefin Polymerization - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Metal Catalysts in Olefin Polymerization write by Zhibin Guan. This book was released on 2009-03-31. Metal Catalysts in Olefin Polymerization available in PDF, EPUB and Kindle. Polyolefin is a major industry that is important for our economy and impacts every aspect of our lives. The discovery of new transition metal-based catalysts is one of the driving forces for the further advancement of this field. Whereas the classical heterogeneous Ziegler-Natta catalysts and homogeneous early transition metal metallocene catalysts remain the workhorses of the polyolefin industry, in roughly the last decade, tremendous progress has been made in developing non-metallocene-based olefin polymerization catalysts. Particularly, the discovery of late transition metal-based olefin polymerization catalysts heralds a new era for this field. These late transition metal complexes not only exhibit high activities rivaling their early metal counterparts, but more importantly they offer unique properties for polymer architectural control and copolymerization with polar olefins. In this book, the most recent major breakthroughs in the development of new olefin polymerization catalysts, including early metal metallocene and non-metallocene complexes and late transition metal complexes, are discussed by leading experts. The authors highlight the most important discoveries in catalysts and their applications in designing new polyolefin-based functional materials.
Transition Metals and Organometallics as Catalysts for Olefin Polymerization
Transition Metals and Organometallics as Catalysts for Olefin Polymerization - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Transition Metals and Organometallics as Catalysts for Olefin Polymerization write by Walter Kaminsky. This book was released on 2012-12-06. Transition Metals and Organometallics as Catalysts for Olefin Polymerization available in PDF, EPUB and Kindle. More than 30 years after the discovery of transition metals and organometal lics as catalysts for olefin polymerization these catalysts did not have lost their fascination. Since 1953 when Karl Ziegler has discovered the catalytic polymerization of ethylene leading to plastically formable polymers which are mechanically stable up to temperatures of about 100°C, synthetic polymers and rubbers have made their way right into private houses. This discovery has been a main impetus for the fast growing production of plastics. The stereoselective poly merization of propylene and other long-chain a-olefins first detected by Giulio Natta leads to an even broadened field of applications. Another enforcing factor were the developments of Standard Oil of Indiana and Phillipps Petroleum Company who engaged in the polymerization of a-olefins supported molybdenum, cobalt and later on chromium catalysts which clearly indicates the wide variety of suitable systems. This kind of research acknowledged merit when in 1963 the Nobel prize of chemistry was awarded to Ziegler and Natta. Although to a great extent there is a technical application for these catalysts, up to now the nature of the active centres and many reaction mechanisms are not completely known.
Handbook of Transition Metal Polymerization Catalysts
Handbook of Transition Metal Polymerization Catalysts - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Handbook of Transition Metal Polymerization Catalysts write by Ray Hoff. This book was released on 2018-04-20. Handbook of Transition Metal Polymerization Catalysts available in PDF, EPUB and Kindle. Including recent advances and historically important catalysts, this book overviews methods for developing and applying polymerization catalysts – dealing with polymerization catalysts that afford commercially acceptable high yields of polymer with respect to catalyst mass or productivity. • Contains the valuable data needed to reproduce syntheses or use the catalyst for new applications • Offers a guide to the design and synthesis of catalysts, and their applications in synthesis of polymers • Includes the information essential for choosing the appropriate reactions to maximize yield of polymer synthesized • Presents new chapters on vanadium catalysts, Ziegler catalysts, laboratory homopolymerization, and copolymerization
Development of Late Transition Metal Catalysts for Olefin Polymerization
Development of Late Transition Metal Catalysts for Olefin Polymerization - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Development of Late Transition Metal Catalysts for Olefin Polymerization write by Shingo Kikukawa. This book was released on 2000. Development of Late Transition Metal Catalysts for Olefin Polymerization available in PDF, EPUB and Kindle.
Olefin Upgrading Catalysis by Nitrogen-based Metal Complexes I
Olefin Upgrading Catalysis by Nitrogen-based Metal Complexes I - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Olefin Upgrading Catalysis by Nitrogen-based Metal Complexes I write by Giuliano Giambastiani. This book was released on 2011-04-29. Olefin Upgrading Catalysis by Nitrogen-based Metal Complexes I available in PDF, EPUB and Kindle. This book highlights key advances that have occurred in the field of olefin conversion in recent years. The role of homogenous transition metal catalysts which contain an imine functionality is emphasized; their potential applications in the processing and upgrade of olefins to a wide variety of commodity products of very high industrial value is also explored. On the threshold of the fiftieth anniversary of the Noble Prize to Ziegler and Natta, this book gives a critical summary of the state of the art developments in the fascinating and rapidly developing field of the olefin polymerization, oligomerization, and co-polymerization catalysis.
