Metal Clusters and Their Reactivity - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Metal Clusters and Their Reactivity write by Zhixun Luo. This book was released on 2020-10-31. Metal Clusters and Their Reactivity available in PDF, EPUB and Kindle. This book discusses current techniques and instrumentation for cluster chemistry. It addresses both the experimental and theoretical aspects of gas-phase metal cluster reactivities, especially those pertaining to pollution removal, energetic reactions and corrosion and anticorrosion. These metal cluster systems have attracted enormous interest as they display a completely new class of physical, chemical, electronic, magnetic and catalytic properties. As these properties change with size and composition, it can thus be understood how their nature evolves from atoms to bulk solids. The book offers readers a basic understanding of the structural chemistry and reactivity of metal clusters in both gas-phase and wet chemistry. Further, the lessons they learn here regarding metal cluster chemistry will prepare researchers for the study of condensed phase dynamics that pertain to wet chemical synthesis, soft-landing deposition and cluster assembly.
Transition Metal Carbonyl Cluster Chemistry
Transition Metal Carbonyl Cluster Chemistry - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Transition Metal Carbonyl Cluster Chemistry write by Paul J. Dyson. This book was released on 2018-10-03. Transition Metal Carbonyl Cluster Chemistry available in PDF, EPUB and Kindle. Transition metal carbonyl clusters (TMCCs) continue to inspire great interest in chemical research, as much for their fascinating structures as for potential industrial applications conferred by their unique properties. This highly accessible book introduces the bonding, structure, spectroscopic properties, and characterization of clusters, and then explores their synthesis, reactivity, reaction mechanisms and use in organic synthesis and catalysis. Transition Metal Carbonyl Cluster Chemistry describes models and rules that correlate cluster structure with electron count, which are then applied in worked examples. Subsequent chapters explain how bonding relates to molecular structure, demonstrate the use of spectroscopic techniques such as NMR, IR and MS in cluster chemistry, and outline the factors contributing to the stability, dynamics and reactivity of clusters. The second part of this book discusses the synthesis and applications of TMCCs. It emphasizes the differences between the reactivities of clusters vs. mononuclear metal complexes, contingent to the availability of multiple-bonding sites and heterosite reactivity. The final chapters discuss reactions in which clusters act as homogeneous catalysts; including discussion on the use of solid and biphasic liquid-liquid supported clusters in heterogeneous catalysts. A useful reference for those commencing further research or post-graduate study on metal carbonyl clusters and advanced organometallic chemistry, this book is also a cornerstone addition to academic and libraries as well as private collections.
The Chemistry of Metal Cluster Complexes
The Chemistry of Metal Cluster Complexes - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook The Chemistry of Metal Cluster Complexes write by Duward F. Shriver. This book was released on 1990. The Chemistry of Metal Cluster Complexes available in PDF, EPUB and Kindle. Seven chapters summarize the current status of organometallic cluster chemistry from the viewpoints of synthesis, structure and bonding, ligand substitution reactions, ligand transformations, polyhedral rearrangement, cluster fragmentation reactions, and metal clusters as homogeneous catalysts. An eighth provides an extensive bibliography of reviews for the period from 1965 to 1988. Annotation copyrighted by Book News, Inc., Portland, OR
The Synergy Between Dynamics and Reactivity at Clusters and Surfaces
The Synergy Between Dynamics and Reactivity at Clusters and Surfaces - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook The Synergy Between Dynamics and Reactivity at Clusters and Surfaces write by L.J. Farrugia. This book was released on 2012-12-06. The Synergy Between Dynamics and Reactivity at Clusters and Surfaces available in PDF, EPUB and Kindle. The analogy between the chemistry of molecular transition metal clusters and the processes of chemisorption and catalysis at metal surfaces (the Cluster Surface analogy) has for a number of years provided an interplay between experimental and theoretical inorganic and physical chemists. This collaborative approach has born fruit in the use of well defined modes of metal-ligand bonding in discrete molecular clusters, models for metal-ligand binding on surfaces. Some of the key topics discussed in The Synergy between Dynamics and Reactivity at Clusters and Surfaces are: (1) Mechanisms of the fluxional behaviour in clusters in the liquid phase and the connections with diffusion processes on extended surfaces. The role of metal-metal bond breaking in diffusion. (2) Analogies in the structure of chemisorbed species and related ligands on metallic clusters. (3) Analogies between benzene surface chemistry on extended metal surfaces and on metal surfaces in molecular cluster compounds with particular reference to structural distortions. (4) The role of mobile precursors for dissociation of chemisorption on extended metals and on clusters. Are there analogies in the ligand attachment during cluster compound synthesis? (5) The role of defect sites on metal surfaces in catalyzing chemical reactions and the connection to the special bonding properties of sites on metal clusters having lowest metal-metal coordination. (6) The size of metal clusters needed to mimic surface phenomena on bulk metal surfaces. Different sites needed for different phenomena.
Structure and Reactivity of Transition Metal Clusters
Structure and Reactivity of Transition Metal Clusters - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Structure and Reactivity of Transition Metal Clusters write by Daniel James Harding. This book was released on 2008. Structure and Reactivity of Transition Metal Clusters available in PDF, EPUB and Kindle.
