Organometallic Pincer Chemistry

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Release : 2012-09-17
Genre : Science
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Book Rating : 818/5 ( reviews)

Organometallic Pincer Chemistry - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Organometallic Pincer Chemistry write by Gerard van Koten. This book was released on 2012-09-17. Organometallic Pincer Chemistry available in PDF, EPUB and Kindle. Gerard van Koten: The Mono-anionic ECE-Pincer Ligand - a Versatile Privileged Ligand Platform: General Considerations.- Elena Poverenov, David Milstein: Non-Innocent Behavior of PCP and PCN Pincer Ligands of Late Metal Complexes.- Dean M. Roddick: Tuning of PCP Pincer Ligand Electronic and Steric Properties.- Gemma R. Freeman, J. A. Gareth Williams: Metal Complexes of Pincer Ligands: Excited States, Photochemistry, and Luminescence.- Davit Zargarian, Annie Castonguay, Denis M. Spasyuk: ECE-Type Pincer Complexes of Nickel.- Roman Jambor and Libor Dostál: The Chemistry of Pincer Complexes of 13 - 15 Main Group Elements.- Kálmán J. Szabo: Pincer Complexes as Catalysts in Organic Chemistry.- Jun-ichi Ito and Hisao Nishiyama: Optically Active Bis(oxazolinyl)phenyl Metal Complexes as Multi-potent Catalysts.- Anthony St. John, Karen I. Goldberg, and D. Michael Heinekey: Pincer Complexes as Catalysts for Amine Borane Dehydrogenation.- Dmitri Gelman and Ronit Romm: PC(sp3)P Transition Metal Pincer Complexes: Properties and Catalytic Applications.- Jennifer Hawk and Steve Craig: Physical Applications of Pincer Complexes.

The Chemistry of Pincer Compounds

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Release : 2011-08-11
Genre : Science
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Book Rating : 157/5 ( reviews)

The Chemistry of Pincer Compounds - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook The Chemistry of Pincer Compounds write by David Morales-Morales. This book was released on 2011-08-11. The Chemistry of Pincer Compounds available in PDF, EPUB and Kindle. Pincer complexes are formed by the binding of a chemical structure to a metal atom with at least one carbon-metal bond. Usually the metal atom has three bonds to a chemical backbone, enclosing the atom like a pincer. The resulting structure protects the metal atom and gives it unique properties.The last decade has witnessed the continuous growth in the development of pincer complexes. These species have passed from being curiosity compounds to chemical chameleons able to perform a wide variety of applications. Their unique metal bound structures provide some of the most active catalysts yet known for organic transformations involving the activation of bonds. The Chemistry of Pincer Compounds details use of pincer compounds including homogeneous catalysis, enantioselective organic transformations, the activation of strong bonds, the biological importance of pincer compounds as potential therapeutic or pharmaceutical agents, dendrimeric and supported materials. * Describes the chemistry and applications of this important class of organometallic and coordination compounds* Covers the areas in which pincer complexes have had an impact* Includes information on more recent and interesting pincer compounds not just those that are well-known

Pincer Compounds

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Release : 2018-04-11
Genre : Science
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Book Rating : 328/5 ( reviews)

Pincer Compounds - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Pincer Compounds write by David Morales-Morales. This book was released on 2018-04-11. Pincer Compounds available in PDF, EPUB and Kindle. Pincer Compounds: Chemistry and Applications offers valuable state-of-the-art coverage highlighting highly active areas of research—from mechanistic work to synthesis and characterization. The book focuses on small molecule activation chemistry (particularly H2 and hydrogenation), earth abundant metals (such as Fe), actinides, carbene-pincers, chiral catalysis, and alternative solvent usage. The book covers the current state of the field, featuring chapters from renowned contributors, covering four continents and ranging from still-active pioneers to new names emerging as creative strong contributors to this fascinating and promising area. Over a decade since the publication of Morales-Morales and Jensen’s The Chemistry of Pincer Compounds (Elsevier 2007), research in this unique area has flourished, finding a plethora of applications in almost every single branch of chemistry—from their traditional application as very robust and active catalysts all the way to potential biological and pharmaceutical applications. Describes the chemistry and applications of this important class of organometallic and coordination compounds Includes contributions from global leaders in the field, featuring pioneers in the area as well as emerging experts conducting exciting research on pincer complexes Highlights areas of promising and active research, including small molecule activation, earth abundant metals, and actinide chemistry

The Privileged Pincer-Metal Platform: Coordination Chemistry & Applications

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Release : 2015-08-27
Genre : Science
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Book Rating : 273/5 ( reviews)

The Privileged Pincer-Metal Platform: Coordination Chemistry & Applications - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook The Privileged Pincer-Metal Platform: Coordination Chemistry & Applications write by Gerard van Koten. This book was released on 2015-08-27. The Privileged Pincer-Metal Platform: Coordination Chemistry & Applications available in PDF, EPUB and Kindle. The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics in pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience. The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors.

Metal-Ligand Co-operativity

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Release : 2021-03-29
Genre : Science
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Book Rating : 166/5 ( reviews)

Metal-Ligand Co-operativity - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Metal-Ligand Co-operativity write by Gerard van Koten. This book was released on 2021-03-29. Metal-Ligand Co-operativity available in PDF, EPUB and Kindle. This book provides researchers in the fields of organic chemistry, organometallic chemistry and homogeneous catalysis with an overview of significant recent developments in the area of metal-ligand cooperativity, with a focus on pincer architectures. The various contributions highlight the widespread impact of M–L co-operativity phenomena on modern organometallic chemistry and catalyst development. The development of efficient and selective catalytic transformations relies on the understanding and fine control of the various elementary reactions that constitutes a catalytic cycle. Co-operative ligands, which actively participate in bond making and bond breaking together to the metal they support, open up new avenues in this area. In particular, buttressing a weak or reactive metal-ligand bond by flanking coordinating arms in a pincer ligand design is proving a versatile strategy to access robust metal complexes that exhibit unusual and selective reactivity patterns.