Phase Equilibria in Chemical Engineering

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Release : 2013-10-22
Genre : Science
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Book Rating : 085/5 ( reviews)

Phase Equilibria in Chemical Engineering - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Phase Equilibria in Chemical Engineering write by Stanley M. Walas. This book was released on 2013-10-22. Phase Equilibria in Chemical Engineering available in PDF, EPUB and Kindle. Phase Equilibria in Chemical Engineering is devoted to the thermodynamic basis and practical aspects of the calculation of equilibrium conditions of multiple phases that are pertinent to chemical engineering processes. Efforts have been made throughout the book to provide guidance to adequate theory and practice. The book begins with a long chapter on equations of state, since it is intimately bound up with the development of thermodynamics. Following material on basic thermodynamics and nonidealities in terms of fugacities and activities, individual chapters are devoted to equilibria primarily between pairs of phases. A few topics that do not fit into these categories and for which the state of the art is not yet developed quantitatively have been relegated to a separate chapter. The chapter on chemical equilibria is pertinent since many processes involve simultaneous chemical and phase equilibria. Also included are chapters on the evaluation of enthalpy and entropy changes of nonideal substances and mixtures, and on experimental methods. This book is intended as a reference and self-study as well as a textbook either for full courses in phase equilibria or as a supplement to related courses in the chemical engineering curriculum. Practicing engineers concerned with separation technology and process design also may find the book useful.

Phase Equilibrium Engineering

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Release : 2013-04-02
Genre : Technology & Engineering
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Book Rating : 71X/5 ( reviews)

Phase Equilibrium Engineering - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Phase Equilibrium Engineering write by Esteban Alberto Brignole. This book was released on 2013-04-02. Phase Equilibrium Engineering available in PDF, EPUB and Kindle. Traditionally, the teaching of phase equilibria emphasizes the relationships between the thermodynamic variables of each phase in equilibrium rather than its engineering applications. This book changes the focus from the use of thermodynamics relationships to compute phase equilibria to the design and control of the phase conditions that a process needs. Phase Equilibrium Engineering presents a systematic study and application of phase equilibrium tools to the development of chemical processes. The thermodynamic modeling of mixtures for process development, synthesis, simulation, design and optimization is analyzed. The relation between the mixture molecular properties, the selection of the thermodynamic model and the process technology that could be applied are discussed. A classification of mixtures, separation process, thermodynamic models and technologies is presented to guide the engineer in the world of separation processes. The phase condition required for a given reacting system is studied at subcritical and supercritical conditions. The four cardinal points of phase equilibrium engineering are: the chemical plant or process, the laboratory, the modeling of phase equilibria and the simulator. The harmonization of all these components to obtain a better design or operation is the ultimate goal of phase equilibrium engineering. Methodologies are discussed using relevant industrial examples The molecular nature and composition of the process mixture is given a key role in process decisions Phase equilibrium diagrams are used as a drawing board for process implementation

Phase Equilibrium in Mixtures

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Release : 2013-10-22
Genre : Technology & Engineering
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Book Rating : 413/5 ( reviews)

Phase Equilibrium in Mixtures - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Phase Equilibrium in Mixtures write by M. B. King. This book was released on 2013-10-22. Phase Equilibrium in Mixtures available in PDF, EPUB and Kindle. Phase Equilibrium in Mixtures deals with phase equilibrium and the methods of correlating, checking, and predicting phase data. Topics covered range from latent heat and vapor pressure to dilute solutions, ideal and near-ideal solutions, and consistency tests. Molecular considerations and their use for the prediction and correlation of data are also discussed. Comprised of nine chapters, this volume begins with an introduction to the role of thermodynamics and the criteria for equilibrium between phases, along with fugacity and the thermodynamic functions of mixing. The discussion then turns to some of the phase phenomena which may be encountered in chemical engineering practice; methods of correlating and extending vapor pressure data and practical techniques for calculating latent heats from these data; the behavior of dilute solutions both at low and high pressures for reacting and non-reacting systems; and the behavior of ideal and near-ideal solutions. The remaining chapters explore non-ideal solutions at normal pressures; practical methods for testing the thermodynamic consistency of phase data; and the extent to which the broad aspects of phase behavior may be interpreted in the light of simple molecular considerations. This book is intended primarily for graduate chemical engineers but should also be of interest to those graduates in physics or chemistry who need to use phase equilibrium data.

Phase Equilibria

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Release : 2023-02-03
Genre : Science
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Book Rating : 064/5 ( reviews)

Phase Equilibria - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Phase Equilibria write by Andreas L. Muhlbauer. This book was released on 2023-02-03. Phase Equilibria available in PDF, EPUB and Kindle. This work provides coverage of experimental and theoretical procedures for vapour-liquid equilibria (VLE). A survey of the different models and approaches in recent literature enables the reader to choose the appropriate action.

Phase Equilibria, Phase Diagrams and Phase Transformations

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Release : 2007-11-22
Genre : Technology & Engineering
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Book Rating : 864/5 ( reviews)

Phase Equilibria, Phase Diagrams and Phase Transformations - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Phase Equilibria, Phase Diagrams and Phase Transformations write by Mats Hillert. This book was released on 2007-11-22. Phase Equilibria, Phase Diagrams and Phase Transformations available in PDF, EPUB and Kindle. Computational tools allow material scientists to model and analyze increasingly complicated systems to appreciate material behavior. Accurate use and interpretation however, requires a strong understanding of the thermodynamic principles that underpin phase equilibrium, transformation and state. This fully revised and updated edition covers the fundamentals of thermodynamics, with a view to modern computer applications. The theoretical basis of chemical equilibria and chemical changes is covered with an emphasis on the properties of phase diagrams. Starting with the basic principles, discussion moves to systems involving multiple phases. New chapters cover irreversible thermodynamics, extremum principles, and the thermodynamics of surfaces and interfaces. Theoretical descriptions of equilibrium conditions, the state of systems at equilibrium and the changes as equilibrium is reached, are all demonstrated graphically. With illustrative examples - many computer calculated - and worked examples, this textbook is an valuable resource for advanced undergraduates and graduate students in materials science and engineering.