Phosphorus(III)Ligands in Homogeneous Catalysis - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Phosphorus(III)Ligands in Homogeneous Catalysis write by Paul C. J. Kamer. This book was released on 2012-05-09. Phosphorus(III)Ligands in Homogeneous Catalysis available in PDF, EPUB and Kindle. Over the last 60 years the increasing knowledge of transition metal chemistry has resulted in an enormous advance of homogeneous catalysis as an essential tool in both academic and industrial fields. Remarkably, phosphorus(III) donor ligands have played an important role in several of the acknowledged catalytic reactions. The positive effects of phosphine ligands in transition metal homogeneous catalysis have contributed largely to the evolution of the field into an indispensable tool in organic synthesis and the industrial production of chemicals. This book aims to address the design and synthesis of a comprehensive compilation of P(III) ligands for homogeneous catalysis. It not only focuses on the well-known traditional ligands that have been explored by catalysis researchers, but also includes promising ligand types that have traditionally been ignored mainly because of their challenging synthesis. Topics covered include ligand effects in homogeneous catalysis and rational catalyst design, P-stereogenic ligands, calixarenes, supramolecular approaches, solid phase synthesis, biological approaches, and solubility and separation. Ligand families covered in this book include phosphine, diphosphine, phosphite, diphosphite, phosphoramidite, phosphonite, phosphinite, phosphole, phosphinine, phosphinidenene, phosphaalkenes, phosphaalkynes, P-chiral ligands, and cage ligands. Each ligand class is accompanied by detailed and reliable synthetic procedures. Often the rate limiting step in the application of ligands in catalysis is the synthesis of the ligands themselves, which can often be very challenging and time consuming. This book will provide helpful advice as to the accessibility of ligands as well as their synthesis, thereby allowing researchers to make a more informed choice. Phosphorus(III) Ligands in Homogeneous Catalysis: Design and Synthesis is an essential overview of this important class of catalysts for academic and industrial researchers working in catalyst development, organometallic and synthetic chemistry.
Homogeneous Catalysis with Metal Phosphine Complexes
Homogeneous Catalysis with Metal Phosphine Complexes - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Homogeneous Catalysis with Metal Phosphine Complexes write by Louis M. Pignolet. This book was released on 2013-11-21. Homogeneous Catalysis with Metal Phosphine Complexes available in PDF, EPUB and Kindle. The field of transition metal catalysis has experienced incredible growth during the past decade. The reasons for this are obvious when one considers the world's energy problems and the need for new and less energy demanding syntheses of important chemicals. Heterogeneous catalysis has played a major industrial role; however, such reactions are generally not selective and are exceedingly difficult to study. Homogeneous catalysis suffers from on-site engineering difficulties; however, such reactions usually provide the desired selectivity. For example, Monsanto's synthesis of optically-active amino acids employs a chiral homogeneous rhodium diphosphine catalyst. Industrial uses of homogeneous catalyst systems are increasing. It is not by accident that many homogeneous catalysts contain tertiary phosphine ligands. These ligands possess the correct steric and electronic properties that are necessary for catalytic reactivity and selectivity. This point will be emphasized throughout the book. Thus the stage is set for a comprehensive be treatment of the many ways in which phosphine catalyst systems can designed, synthesized, and studied.
Phosphorus(iii) Ligands in Homogeneous Catalysis
Phosphorus(iii) Ligands in Homogeneous Catalysis - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Phosphorus(iii) Ligands in Homogeneous Catalysis write by Paul Kamer. This book was released on 2012-07-01. Phosphorus(iii) Ligands in Homogeneous Catalysis available in PDF, EPUB and Kindle. Over the last 60 years the increasing knowledge of transition metal chemistry has resulted in an enormous advance of homogeneous catalysis as an essential tool in both academic and industrial fields. Remarkably, phosphorus(III) donor ligands have played an important role in several of the acknowledged catalytic reactions. The positive effects of phosphine ligands in transition metal homogeneous catalysis have contributed largely to the evolution of the field into an indispensable tool in organic synthesis and the industrial production of chemicals. This book aims to address the design and synthesis of a comprehensive compilation of P(III) ligands for homogeneous catalysis. It not only focuses on the well-known traditional ligands that have been explored by catalysis researchers, but also includes promising ligand types that have traditionally been ignored mainly because of their challenging synthesis. Topics covered include ligand effects in homogeneous catalysis and rational catalyst design, P-stereogenic ligands, calixarenes, supramolecular approaches, solid phase synthesis, biological approaches, and solubility and separation. Ligand families covered in this book include phosphine, diphosphine, phosphite, diphosphite, phosphoramidite, phosphonite, phosphinite, phosphole, phosphinine, phosphinidenene, phosphaalkenes, phosphaalkynes, P-chiral ligands, and cage ligands. Each ligand class is accompanied by detailed and reliable synthetic procedures. Often the rate limiting step in the application of ligands in catalysis is the synthesis of the ligands themselves, which can often be very challenging and time consuming. This book will provide helpful advice as to the accessibility of ligands as well as their synthesis, thereby allowing researchers to make a more informed choice. "Phosphorus(III) Ligands in Homogeneous Catalysis: Design and Synthesis" is an essential overview of this important class of catalysts for academic and industrial researchers working in catalyst development, organometallic and synthetic chemistry.
Phosphorus Compounds
Phosphorus Compounds - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Phosphorus Compounds write by Maurizio Peruzzini. This book was released on 2011-06-10. Phosphorus Compounds available in PDF, EPUB and Kindle. Each chapter of Phosphorus Compounds: Advanced Tools in Catalysis and Material Sciences have been carefully selected by the editors in order to represent a state-of-the-art overview of how phosphorus chemistry can provide solutions in various fields of applications. The editors have assembled an international array of world-renowned scientists and each chapter is written by experts in the fields of synthetic chemistry, homogeneous catalysis, dendrimers, theoretical calculations, materials science, and medicinal chemistry with a special focus on the chemistry of phosphorus compounds. Phosphorus Compounds: Advanced Tools in Catalysis and Material Sciences is of interest to a general readership ranging from advanced university course students to experts in academia and industry.
Phosphorus Ligands in Asymmetric Catalysis
Phosphorus Ligands in Asymmetric Catalysis - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Phosphorus Ligands in Asymmetric Catalysis write by Armin Börner. This book was released on 2008. Phosphorus Ligands in Asymmetric Catalysis available in PDF, EPUB and Kindle.
