Organometallic Bonding and Reactivity - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Organometallic Bonding and Reactivity write by J.M. Brown. This book was released on 2003-07-01. Organometallic Bonding and Reactivity available in PDF, EPUB and Kindle. The making and breaking of carbon-metal bonds is fundamental to all the processes of organometallic chemistry and metal mediated homogeneous or heterogeneous catalysis. The ever expanding scope of highly specific stoichiometric and catalytic transformations or organic substrates involving metals requires a thorough physical and theoretical understanding of fundamental principles of organometallic structure and reactivity. Diffraction experiments form the basis of tailoring the molecular architecture of organometallic compounds for specific functions. Mass spectrometric techniques possess the power to provide direct information on the energetics of transient species generated in the gas-phase. Computational chemistry with ab initio or density functional methods make a reliable numerical assessment of structures and (relative) energies increasingly feasible. Embedding methods, combining quantum chemistry with force field of semiempirical MO treatments, quantum dynamic studies and the computational modelling of solvent effects extend the utility of the basic methods. This volume in the series Topics in Organometallic Chemistry presents a survey by renowned experts of important experimental and theoretical developments to elucidate basic aspects of bonding, energetics, reaction mechanisms, molecular geometries and solid-state structures of organometallic compounds. Written by authors with frontier research expertise in their fields, both experimental and quantum chemical techniques, methodologies, results and interpretations are detailed in a manner suitable for the non-specialist, who seeks state-of-the-art information in the respective field.
Reactivity and Bonding in Transition Organometallic Compounds
Reactivity and Bonding in Transition Organometallic Compounds - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Reactivity and Bonding in Transition Organometallic Compounds write by . This book was released on 1970. Reactivity and Bonding in Transition Organometallic Compounds available in PDF, EPUB and Kindle.
Transition Metal Carbonyl Cluster Chemistry
Transition Metal Carbonyl Cluster Chemistry - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Transition Metal Carbonyl Cluster Chemistry write by Paul J. Dyson. This book was released on 2018-10-03. Transition Metal Carbonyl Cluster Chemistry available in PDF, EPUB and Kindle. Transition metal carbonyl clusters (TMCCs) continue to inspire great interest in chemical research, as much for their fascinating structures as for potential industrial applications conferred by their unique properties. This highly accessible book introduces the bonding, structure, spectroscopic properties, and characterization of clusters, and then explores their synthesis, reactivity, reaction mechanisms and use in organic synthesis and catalysis. Transition Metal Carbonyl Cluster Chemistry describes models and rules that correlate cluster structure with electron count, which are then applied in worked examples. Subsequent chapters explain how bonding relates to molecular structure, demonstrate the use of spectroscopic techniques such as NMR, IR and MS in cluster chemistry, and outline the factors contributing to the stability, dynamics and reactivity of clusters. The second part of this book discusses the synthesis and applications of TMCCs. It emphasizes the differences between the reactivities of clusters vs. mononuclear metal complexes, contingent to the availability of multiple-bonding sites and heterosite reactivity. The final chapters discuss reactions in which clusters act as homogeneous catalysts; including discussion on the use of solid and biphasic liquid-liquid supported clusters in heterogeneous catalysts. A useful reference for those commencing further research or post-graduate study on metal carbonyl clusters and advanced organometallic chemistry, this book is also a cornerstone addition to academic and libraries as well as private collections.
Organometallic Bonding and Reactivity
Organometallic Bonding and Reactivity - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Organometallic Bonding and Reactivity write by J.M. Brown. This book was released on 2013-10-03. Organometallic Bonding and Reactivity available in PDF, EPUB and Kindle. General The making and breaking of carbon-metal bonds is fundamental to all the p- cesses of organometallic chemistry and moreover plays a significant role in - mogeneous as well as heterogeneous catalysis. This rather blunt statement - phasises the extent to which a proper understanding of the structure, energetics and reactivity of C-M bonds is at the core of the discipline. In order to accept it, a proper definition of the terms involved is required. Quite simply we define the metal-carbon bond in its broadest sense to embrace carbon linked to transiti- metals, lanthanides and actinides, and main group metals. We do not dist- guish between formally covalent single or multiple bonding on the one hand and q-bonding on the other. In the studies to be described in the following chapters, the emphasis will be on transition metal complexes and insofar as the fun- mentals come under scrutiny, simple metal alkyls or related species (metal al- nyl, alkynyl, aryl, or allyl) will play an emphatic part. The central role of metal alkyls and their congeners and especially the role of their metal carbon linkage in homogeneous catalysis may be appreciated by considering some key reaction steps leading to their formation or breakdown. There follows a few prominent examples of transition metal mediated stoichiometric or catalytic processes: - In homogeneous hydrogenation of double bonds, the stepwise reaction of an q2-coordinated alkene with dihydrogen gives first an alkyl metal hydride, and then the decoordinated alkane by elimination.
Organotransition Metal Chemistry: From Bonding to Catalysis
Organotransition Metal Chemistry: From Bonding to Catalysis - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Organotransition Metal Chemistry: From Bonding to Catalysis write by John F. Hartwig. This book was released on 2010-02-10. Organotransition Metal Chemistry: From Bonding to Catalysis available in PDF, EPUB and Kindle. Based on Collman et al.'s best-selling classic book, Principles and Applications of Organotransition Metal Chemistry, Hartwig's text consists of new or thoroughly updated and restructured chapters and provides an in-depth view into mechanism, reaction scope, and applications. It covers the most important developments in the field over the last twenty years with great clarity with a selective, but thorough and authoritative coverage of the fundamentals of organometallic chemistry, the elementary reactions of these complexes, and many catalytic processes occurring through organometallic intermediates, making this the Organotransition Metal Chemistry text for a new generation of scientists.
