Reactivity of Ylenes at Late Transition Metal Centers - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Reactivity of Ylenes at Late Transition Metal Centers write by Burgert Blom. This book was released on 2011-10-31. Reactivity of Ylenes at Late Transition Metal Centers available in PDF, EPUB and Kindle.
Synthesis, Characterization and Reactivity of Ylidyne and μ-Ylido Complexes Supported by Scorpionato Ligands
Synthesis, Characterization and Reactivity of Ylidyne and μ-Ylido Complexes Supported by Scorpionato Ligands - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Synthesis, Characterization and Reactivity of Ylidyne and μ-Ylido Complexes Supported by Scorpionato Ligands write by Priyabrata Ghana. This book was released on 2018-12-11. Synthesis, Characterization and Reactivity of Ylidyne and μ-Ylido Complexes Supported by Scorpionato Ligands available in PDF, EPUB and Kindle. This book explores the development of the first open-shell heavier tetrylidyne complexes featuring a tetrel-centered unpaired electron, and unprecedented metallatetrylidynes containing a multiply-bonded, linear-coordinated single heavier tetrel atom embedded between two metal centers. The chemistry of compounds featuring triple bonds of the heavier Group-14 elements Si–Pb with transition metals is a very challenging research area, which combines modern molecular main-group element with transition-metal chemistry, and is of fundamental importance for the understanding of chemical bonding. During the last 15 years, the research in this area has witnessed considerable progress in isolating a series of closed-shell tetrylidyne complexes. However, despite numerous attempts, open-shell tetrylidyne complexes and heavier group 14 element congeners of metallacarbynes and carbide complexes remained inaccessible. In this book, readers will find more about the synthesis, full characterization and reactivity studies of these novel complexes that uncovered a plethora of exceptional products, including a novel m3-silicido complex, the first dimetallasilacumulene with a linear, two-coordinated single silicon atom and the first compounds of planar tetracoordinated silicon (ptSi) (Anti-van’t Hoff-Le Bell Silicon). Readers will also learn about the isolation and full characterization of the first room-temperature stable disilavinylidene, a silicon analogue of the very reactive vinylidenes (R2C=C:), and the first intermetallic plumbylidyne ligand transfer reactions.
Synthesis and Reactivity of Late Transition Metal Complexes Featuring a Bis(8-quinolyl)methylsilyl Ligand
Synthesis and Reactivity of Late Transition Metal Complexes Featuring a Bis(8-quinolyl)methylsilyl Ligand - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Synthesis and Reactivity of Late Transition Metal Complexes Featuring a Bis(8-quinolyl)methylsilyl Ligand write by Preeyanuch Sangtrirutnugul. This book was released on 2007. Synthesis and Reactivity of Late Transition Metal Complexes Featuring a Bis(8-quinolyl)methylsilyl Ligand available in PDF, EPUB and Kindle.
Coordination Chemistry of Silicon
Coordination Chemistry of Silicon - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Coordination Chemistry of Silicon write by Prof. Dr. Shigeyoshi Inoue. This book was released on 2019-03-04. Coordination Chemistry of Silicon available in PDF, EPUB and Kindle. The chemistry of silicon has always been a field of major concern due to its proximity to carbon on the periodic table. From the molecular chemist’s viewpoint, one of the most interesting differences between carbon and silicon is their divergent coordination behavior. In fact, silicon is prone to form hyper-coordinate organosilicon complexes, and, as conveyed by reports in the literature, highly sophisticated ligand systems are required to furnish low-coordinate organosilicon complexes. Tremendous progress in experimental, as well as computational, techniques has granted synthetic access to a broad range of coordination numbers for silicon, and the scientific endeavor, which was ongoing for decades, was rewarded with landmark discoveries in the field of organosilicon chemistry. Molecular congeners of silicon(0), as well as silicon oxides, were unveiled, and the prominent group 14 metalloid proved its applicability in homogenous catalysis as a supportive ligand or even as a center of catalytic activity. This book focuses on the most recent advances in the coordination chemistry of silicon with transition metals as well as main group elements, including the stabilization of low-valent silicon species through the coordination of electron donor ligands. Therefore, this book is associated with the development of novel synthetic methodologies, structural elucidations, bonding analysis, and also possible applications in catalysis or chemical transformations using related organosilicon compounds.
Late Transition Metal Coordination Chemistry and Reactivity of Bis(diphenylphosphino)alkylamine Ligands
Late Transition Metal Coordination Chemistry and Reactivity of Bis(diphenylphosphino)alkylamine Ligands - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Late Transition Metal Coordination Chemistry and Reactivity of Bis(diphenylphosphino)alkylamine Ligands write by Daniel Carl Frankel. This book was released on 1993. Late Transition Metal Coordination Chemistry and Reactivity of Bis(diphenylphosphino)alkylamine Ligands available in PDF, EPUB and Kindle.
