Solar Hydrogen Production by Photo-oxidation of Water from Doped Iron Oxide Photoanodes - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Solar Hydrogen Production by Photo-oxidation of Water from Doped Iron Oxide Photoanodes write by Alan Kleiman-Shwarsctein. This book was released on 2010. Solar Hydrogen Production by Photo-oxidation of Water from Doped Iron Oxide Photoanodes available in PDF, EPUB and Kindle. Hematite thin film electrodes synthesized as photoanodes for the photoelectrochemical hydrogen production from water. A novel electrochemical method in which the iron oxide precursors is co-deposited with diverse metals to create electrochemically doped thin films has been studies. The most promising dopant metals that found have been Pt, Mo, Cr, Ti and Al; which are substituted into the hematite structure in 1-8 % atomic. The films were characterized by scanning electron microscopy, X-ray diffraction, UV-Vis optical spectroscopy, Raman spectroscopy and X-ray photoelectron spectroscopy to determine the effect of the dopants on the hematite structure and the photoelectrochemical performance as compared to the undoped material. The IPCE (incident photon-to-current efficiency) values of the transition metal doped iron oxide were up to 4 times higher than the undoped samples. Further improvements to the photocatalytic performance were achieved by deposition of oxygen evolution catalysts, as well as modifications to the surface of the hematite photoelectrode.
On the Design of Oxide Films, Nanomaterials, and Heterostructures for Solar Water Oxidation Photoanodes
On the Design of Oxide Films, Nanomaterials, and Heterostructures for Solar Water Oxidation Photoanodes - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook On the Design of Oxide Films, Nanomaterials, and Heterostructures for Solar Water Oxidation Photoanodes write by Coleman Kronawitter. This book was released on 2012. On the Design of Oxide Films, Nanomaterials, and Heterostructures for Solar Water Oxidation Photoanodes available in PDF, EPUB and Kindle. Photoelectrochemistry and its associated technologies show unique potential to facilitate the large-scale production of solar fuels - those energy-rich chemicals obtained through conversion processes driven by solar energy, mimicking the photosynthetic process of green plants. The critical component of photoelectrochemical devices designed for this purpose is the semiconductor photoelectrode, which must be optically absorptive, chemically stable, and possess the required electronic band alignment with respect to the redox couple of the electrolyte to drive the relevant electrochemical reactions. After many decades of investigation, the primary technological obstacle remains the development of photoelectrode structures capable of efficient and stable conversion of light with visible frequencies, which is abundant in the solar spectrum. Metal oxides represent one of the few material classes that can be made photoactive and remain stable to perform the required functions. The unique range of functional properties of oxides, and especially the oxides of transition metals, relates to their associated diversity of cation oxidation states, cation electronic configurations, and crystal structures. In this dissertation, the use of metal oxide films, nanomaterials, and heterostructures in photoelectrodes enabling the solar-driven oxidation of water and generation of hydrogen fuel is examined. A range of transition- and post-transition-metal oxide material systems and nanoscale architectures is presented. The first chapters present results related to electrodes based on alpha-phase iron(III) oxide, a promising visible-light-active material widely investigated for this application. Studies of porous films fabricated by physical vapor deposition reveal the importance of structural quality, as determined by the deposition substrate temperature, on photoelectrochemical performance. Heterostructures with nanoscale feature dimensionality are explored and reviewed in a later chapter, which describes the methodologies to combine the unique and complimentary functional properties of dissimilar oxides to optimize the water photo-oxidation process Experimental results based on an iron(III) oxide-tungsten(VI) oxide system show enhancements associated with the heterostructure, which may indicate the presence of unexpected minority carrier dynamics, as observed additionally by ultrafast transient absorption spectroscopy. Next, a new conceptual framework for the design of solar water oxidation photoelectrodes based on the spatially inhomogeneous doping of wide-bandgap metal oxide nanostructures is introduced and experimentally verified. It is found that optical absorption and electronic conduction can be decoupled and optimized by spatially segregating the functional impurity species that facilitate their associated physical processes. In the final chapters of this dissertation the electronic structures of key oxide-oxide interfaces, relevant to the operation of efficient photoanodes, are examined using synchrotron-based soft x-ray spectroscopy. These studies indicate that the interfacial regions of electrodes possess distinct electronic structures, which deviate in terms of orbital character and occupancy from those of their constituent bulk oxides. These observations inform methodology to address certain operational deficiencies associated with the use of metal oxides for solar energy conversion applications.
Solar Hydrogen Generation: Transition Metal Oxides in Water Photoelectrolysis
Solar Hydrogen Generation: Transition Metal Oxides in Water Photoelectrolysis - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Solar Hydrogen Generation: Transition Metal Oxides in Water Photoelectrolysis write by Jinghua Guo. This book was released on 2012-01-27. Solar Hydrogen Generation: Transition Metal Oxides in Water Photoelectrolysis available in PDF, EPUB and Kindle. State-of-the-art renewable energy science research and applications Solar Hydrogen Generation: Transition Metal Oxides in Water Photoelectrolysis provides expert techniques for extracting hydrogen from water using transition metal oxides as catalysts. The basic processes of electrochemistry and photocatalysis for hydrogen production are described along with photocatalytic reactions and semiconductor photocatalysts, particularly metal oxides. This in-depth guide illustrates the corresponding crystal structure vs. electronic structure and optical properties vs. light absorption of transition metal oxides. Impurity and doped photocatalysts, integrated organic and inorganic systems, surface and interface chemistry, and nanostructure and morphology in photocatalysis applications are all addressed. This comprehensive resource introduces soft x-ray absorption (XAS), soft x-ray emission spectroscopy (XES), and resonant inelastic soft x-ray scattering (RIXS), followed by a description of instrumentation. COVERAGE INCLUDES: * Hydrogen generation: electrochemistry and photoelectrolysis * Photocatalytic reactions, oxidation, and reduction * Transition metal oxides * Crystal structure and electronic structure * Optical properties and light absorption * Impurity, dopants, and defects * Surface and morphology * Soft x-ray spectroscopy and electronic structure
Photoelectrochemical Hydrogen Production
Photoelectrochemical Hydrogen Production - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Photoelectrochemical Hydrogen Production write by Roel van de Krol. This book was released on 2011-11-09. Photoelectrochemical Hydrogen Production available in PDF, EPUB and Kindle. Photoelectrochemical Hydrogen Production describes the principles and materials challenges for the conversion of sunlight into hydrogen through water splitting at a semiconducting electrode. Readers will find an analysis of the solid state properties and materials requirements for semiconducting photo-electrodes, a detailed description of the semiconductor/electrolyte interface, in addition to the photo-electrochemical (PEC) cell. Experimental techniques to investigate both materials and PEC device performance are outlined, followed by an overview of the current state-of-the-art in PEC materials and devices, and combinatorial approaches towards the development of new materials. Finally, the economic and business perspectives of PEC devices are discussed, and promising future directions indicated. Photoelectrochemical Hydrogen Production is a one-stop resource for scientists, students and R&D practitioners starting in this field, providing both the theoretical background as well as useful practical information on photoelectrochemical measurement techniques. Experts in the field benefit from the chapters on current state-of-the-art materials/devices and future directions.
Nanotechnology for Hydrogen Production and Storage
Nanotechnology for Hydrogen Production and Storage - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Nanotechnology for Hydrogen Production and Storage write by Kamel A. Abd-Elsalam. This book was released on 2024-05-01. Nanotechnology for Hydrogen Production and Storage available in PDF, EPUB and Kindle. Nanotechnology for Hydrogen Production and Storage: Nanostructured Materials and Interfaces presents an evaluation of the various nano-based systems for hydrogen generation and storage. With a focus on the challenges and recent developments, the book analyses nanomaterials with the potential to boost hydrogen production and improve storage. The book assesses the potential improvements to industrially important hydrogen production technologies by the way of better surface-interface control through nanostructures of strategical composites of metal oxides, metal chalcogenides, plasmonic metals, conducting polymers, carbonaceous materials and bio-interfaces with different types of algae and bacteria. The efficiency of various photochemical water splitting processes to generate renewable hydrogen energy are reviewed, with a focus on natural water splitting via photosynthesis, and the use of various metallic and non-metallic nanomaterials in anthropogenic/artificial water splitting processes is analyzed. The potential of nanomaterials in enhancing hydrogen generation in dark- and photo-fermentative organisms is also explored. Finally, the book critically evaluates various nano-based systems for hydrogen generation, as well as significant challenges and recent advances in biohydrogen research and development. Nanotechnology for Hydrogen Production and Storage is a valuable reference for student and researchers working in renewable energy and interested in the production and storage of hydrogen and may be of interest to interdisciplinary researchers in the areas of environmental engineering, materials science, and biotechnology. Synthesizes the latest advances in the field of nanoparticles for hydrogen production and storage, including new methods and industry applications Explains various methods for the design of nanomaterials for hydrogen production and storage Identifies the strengths and weaknesses of different nanomaterials and approaches Explores hydrogen production via photocatalytic, electrocatalytic, and biological processes
