Solvation Effects on Molecules and Biomolecules - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Solvation Effects on Molecules and Biomolecules write by Sylvio Canuto. This book was released on 2010-07-03. Solvation Effects on Molecules and Biomolecules available in PDF, EPUB and Kindle. This volume is an interdisciplinary treatise on the theoretical approach to solvation problems. It describes the essential details of the theoretical methods and places them into the context of modern applications, and hence is of broad interest to theoreticians and experimentalists. The assembly of these modern methods and applications into one volume is a unique contribution to date and gives a broad and ample description of the field in its present stage of development.
Molecular Theory of Solvation
Molecular Theory of Solvation - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Molecular Theory of Solvation write by F. Hirata. This book was released on 2006-04-11. Molecular Theory of Solvation available in PDF, EPUB and Kindle. Molecular Theory of Solvation presents the recent progress in the statistical mechanics of molecular liquids applied to the most intriguing problems in chemistry today, including chemical reactions, conformational stability of biomolecules, ion hydration, and electrode-solution interface. The continuum model of "solvation" has played a dominant role in describing chemical processes in solution during the last century. This book discards and replaces it completely with molecular theory taking proper account of chemical specificity of solvent. The main machinery employed here is the reference-interaction-site-model (RISM) theory, which is combined with other tools in theoretical chemistry and physics: the ab initio and density functional theories in quantum chemistry, the generalized Langevin theory, and the molecular simulation techniques. This book will be of benefit to graduate students and industrial scientists who are struggling to find a better way of accounting and/or predicting "solvation" properties.
Solvent Effects and Chemical Reactivity
Solvent Effects and Chemical Reactivity - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Solvent Effects and Chemical Reactivity write by Orlando Tapia. This book was released on 2006-04-11. Solvent Effects and Chemical Reactivity available in PDF, EPUB and Kindle. This book gathers original contributions from a selected group of distinguished researchers that are actively working in the theory and practical applications of solvent effects and chemical reactions. The importance of getting a good understanding of surrounding media effects on chemical reacting system is difficult to overestimate. Applications go from condensed phase chemistry, biochemical reactions in vitro to biological systems in vivo. Catalysis is a phenomenon produced by a particular system interacting with the reacting subsystem. The result may be an increment of the chemical rate or sometimes a decreased one. At the bottom, catalytic sources can be characterized as a special kind of surrounding medium effect. The materials involving in catalysis may range from inorganic components as in zeolites, homogenous components, enzymes, catalytic antibodies, and ceramic materials. . With the enormous progress achieved by computing technology, an increasing number of models and phenomenological approaches are being used to describe the effects of a given surrounding medium on the electronic properties of selected subsystem. A number of quantum chemical methods and programs, currently applied to calculate in vacuum systems, have been supplemented with a variety of model representations. With the increasing number of methodologies applied to this important field, it is becoming more and more difficult for non-specialist to cope with theoretical developments and extended applications. For this and other reasons, it is was deemed timely to produce a book where methodology and applications were analyzed and reviewed by leading experts in the field.
The Chemical Physics of Solvation
The Chemical Physics of Solvation - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook The Chemical Physics of Solvation write by Revaz R. Dogonadze. This book was released on 1985. The Chemical Physics of Solvation available in PDF, EPUB and Kindle. The importance of solvation as a concept which covers quite generally the interactions between a molecular solute particle and a macroscopic body of surrounding solvent is well recognized. Solvation plays a major role in the distribution of elements in the geo- and hydrosphere, and most chemical and biological processes involve solvated reactants and products, the electronic and molecular structure of which are strongly determined by solvation. This three-volume monograph has been written collectively by 50 authors from 14 countries who are specialists in different areas of solvation science. Part A deals with the theory of solvation; Part B is entirely devoted to spectroscopy of solvation; and Part C covers solvation phenomena in specific physical, chemical and biological systems. The volumes will be an invaluable reference source for physicists, physical chemists and biophysicists undertaking investigations into the diversified and fascinating areas of the physics and chemical physics of solvation at postgraduate and professional research levels.
Solvent Effects on Chemical Phenomena
Solvent Effects on Chemical Phenomena - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Solvent Effects on Chemical Phenomena write by Edward Amis. This book was released on 2012-12-02. Solvent Effects on Chemical Phenomena available in PDF, EPUB and Kindle. Solvent Effects on Chemical Phenomena, Volume I discusses the developments in the understanding of solvent effects on chemical phenomena in solution. This five-chapter volume begins with a discussion on the general concepts of various solvation types, including positive and negative, inner and outer sphere, and mixed component. The subsequent chapter deals with the determination of the actual solvation number for single ions. A short list of the total effective hydration numbers of electrolytes determined from temperature dependence of proton shifts is also provided in this chapter. Another chapter presents a number of examples of the unusual properties of certain mixed aqueous systems. The solvent effects on reaction rates and mechanisms are highlighted in the concluding chapter. This chapter also covers various types of solvents, such as protic and dipolar aprotic. The enthalpy and entropy of activation in salvation and the Finkelstein reactions are also discussed. Research chemists and scientists, teachers, and students with courses in solution chemistry will greatly benefit from this volume.
