Solvent Effects and Chemical Reactivity

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Release : 2006-04-11
Genre : Science
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Book Rating : 316/5 ( reviews)

Solvent Effects and Chemical Reactivity - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Solvent Effects and Chemical Reactivity write by Orlando Tapia. This book was released on 2006-04-11. Solvent Effects and Chemical Reactivity available in PDF, EPUB and Kindle. This book gathers original contributions from a selected group of distinguished researchers that are actively working in the theory and practical applications of solvent effects and chemical reactions. The importance of getting a good understanding of surrounding media effects on chemical reacting system is difficult to overestimate. Applications go from condensed phase chemistry, biochemical reactions in vitro to biological systems in vivo. Catalysis is a phenomenon produced by a particular system interacting with the reacting subsystem. The result may be an increment of the chemical rate or sometimes a decreased one. At the bottom, catalytic sources can be characterized as a special kind of surrounding medium effect. The materials involving in catalysis may range from inorganic components as in zeolites, homogenous components, enzymes, catalytic antibodies, and ceramic materials. . With the enormous progress achieved by computing technology, an increasing number of models and phenomenological approaches are being used to describe the effects of a given surrounding medium on the electronic properties of selected subsystem. A number of quantum chemical methods and programs, currently applied to calculate in vacuum systems, have been supplemented with a variety of model representations. With the increasing number of methodologies applied to this important field, it is becoming more and more difficult for non-specialist to cope with theoretical developments and extended applications. For this and other reasons, it is was deemed timely to produce a book where methodology and applications were analyzed and reviewed by leading experts in the field.

Solvents and Solvent Effects in Organic Chemistry

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Release : 2006-03-06
Genre : Science
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Book Rating : 673/5 ( reviews)

Solvents and Solvent Effects in Organic Chemistry - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Solvents and Solvent Effects in Organic Chemistry write by Christian Reichardt. This book was released on 2006-03-06. Solvents and Solvent Effects in Organic Chemistry available in PDF, EPUB and Kindle. In most cases, every chemist must deal with solvent effects, whether voluntarily or otherwise. Since its publication, this has been the standard reference on all topics related to solvents and solvent effects in organic chemistry. Christian Reichardt provides reliable information on the subject, allowing chemists to understand and effectively use these phenomena. 3rd updated and enlarged edition of a classic 35% more contents excellent, proven concept includes current developments, such as ionic liquids indispensable in research and industry From the reviews of the second edition: "...This is an immensely useful book, and the source that I would turn to first when seeking virtually any information about solvent effects." —Organometallics

Solvent Effects in Chemistry: Advances in Applications and Research

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Release : 2020-08-26
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Book Rating : 262/5 ( reviews)

Solvent Effects in Chemistry: Advances in Applications and Research - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Solvent Effects in Chemistry: Advances in Applications and Research write by Valérie Mireault. This book was released on 2020-08-26. Solvent Effects in Chemistry: Advances in Applications and Research available in PDF, EPUB and Kindle. In Solvent Effects in Chemistry: Advances in Applications and Research, a critical review of solvent influence on the performance of metal catalysts in the hydrogenation of carbonyl compounds, specifically unsaturated aldehydes, ketones and ketoesters, is provided.Additionally, the effects of solvent on the kinetics and mechanism of different reactions, stability, and sensitivity of the nanostructures are investigated.The uses of a large of variety of solvents varying from non-polar low basic solvents to polar strong basic solvents are discussed, showing that the properties of different solvents strongly influence the product composition of both studied reactions.The effects of solvent on the isomerization of monoterpenes epoxides as α- and β-pinene epoxide, limonene epoxide, verbenol epoxide, and nopol epoxide are explained from molecular and mechanistic points of view.The concluding study explores how heterolytic bond dissociation forms ionic species, while the corresponding homolytic bond dissociation results in the formation of neutral radical species.

Solvent Effects in Chemistry

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Release : 2015-08-03
Genre : Technology & Engineering
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Book Rating : 986/5 ( reviews)

Solvent Effects in Chemistry - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Solvent Effects in Chemistry write by Erwin Buncel. This book was released on 2015-08-03. Solvent Effects in Chemistry available in PDF, EPUB and Kindle. This book introduces the concepts, theory and experimental knowledge concerning solvent effects on the rate and equilibrium of chemical reactions of all kinds. It begins with basic thermodynamics and kinetics, building on this foundation to demonstrate how a more detailed understanding of these effects may be used to aid in determination of reaction mechanisms, and to aid in planning syntheses. Consideration is given to theoretical calculations (quantum chemistry, molecular dynamics, etc.), to statistical methods (chemometrics), and to modern day concerns such as "green" chemistry, where utilization and disposal of chemical waste or by-products in an environmentally safe way is as important as achieving the desired end products by all chemists nowadays. The treatment progresses from elementary to advanced material in straightforward fashion. The more advanced topics are not developed in an overly rigorous way so that upper-level undergraduates, graduates, and newcomers to the field can grasp the concepts easily.

Solvent Effects in Chemistry

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Release : 2016
Genre : Chemical reactions
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Book Rating : 551/5 ( reviews)

Solvent Effects in Chemistry - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Solvent Effects in Chemistry write by E. Buncel. This book was released on 2016. Solvent Effects in Chemistry available in PDF, EPUB and Kindle.