Solvent Effects on Chemical Phenomena

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Release : 2012-12-02
Genre : Science
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Book Rating : 522/5 ( reviews)

Solvent Effects on Chemical Phenomena - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Solvent Effects on Chemical Phenomena write by Edward Amis. This book was released on 2012-12-02. Solvent Effects on Chemical Phenomena available in PDF, EPUB and Kindle. Solvent Effects on Chemical Phenomena, Volume I discusses the developments in the understanding of solvent effects on chemical phenomena in solution. This five-chapter volume begins with a discussion on the general concepts of various solvation types, including positive and negative, inner and outer sphere, and mixed component. The subsequent chapter deals with the determination of the actual solvation number for single ions. A short list of the total effective hydration numbers of electrolytes determined from temperature dependence of proton shifts is also provided in this chapter. Another chapter presents a number of examples of the unusual properties of certain mixed aqueous systems. The solvent effects on reaction rates and mechanisms are highlighted in the concluding chapter. This chapter also covers various types of solvents, such as protic and dipolar aprotic. The enthalpy and entropy of activation in salvation and the Finkelstein reactions are also discussed. Research chemists and scientists, teachers, and students with courses in solution chemistry will greatly benefit from this volume.

Solvent Effects on Chemical Phenomena

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Author :
Release : 1973
Genre : Solution (Chemistry)
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Book Rating : 011/5 ( reviews)

Solvent Effects on Chemical Phenomena - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Solvent Effects on Chemical Phenomena write by Edward Stephen Amis. This book was released on 1973. Solvent Effects on Chemical Phenomena available in PDF, EPUB and Kindle. Solvent Effects on Chemical Phenomena ...

Solvents and Solvent Effects in Organic Chemistry

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Release : 2006-03-06
Genre : Science
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Book Rating : 673/5 ( reviews)

Solvents and Solvent Effects in Organic Chemistry - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Solvents and Solvent Effects in Organic Chemistry write by Christian Reichardt. This book was released on 2006-03-06. Solvents and Solvent Effects in Organic Chemistry available in PDF, EPUB and Kindle. In most cases, every chemist must deal with solvent effects, whether voluntarily or otherwise. Since its publication, this has been the standard reference on all topics related to solvents and solvent effects in organic chemistry. Christian Reichardt provides reliable information on the subject, allowing chemists to understand and effectively use these phenomena. 3rd updated and enlarged edition of a classic 35% more contents excellent, proven concept includes current developments, such as ionic liquids indispensable in research and industry From the reviews of the second edition: "...This is an immensely useful book, and the source that I would turn to first when seeking virtually any information about solvent effects." —Organometallics

Solvent Effects and Chemical Reactivity

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Release : 2006-04-11
Genre : Science
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Book Rating : 316/5 ( reviews)

Solvent Effects and Chemical Reactivity - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Solvent Effects and Chemical Reactivity write by Orlando Tapia. This book was released on 2006-04-11. Solvent Effects and Chemical Reactivity available in PDF, EPUB and Kindle. This book gathers original contributions from a selected group of distinguished researchers that are actively working in the theory and practical applications of solvent effects and chemical reactions. The importance of getting a good understanding of surrounding media effects on chemical reacting system is difficult to overestimate. Applications go from condensed phase chemistry, biochemical reactions in vitro to biological systems in vivo. Catalysis is a phenomenon produced by a particular system interacting with the reacting subsystem. The result may be an increment of the chemical rate or sometimes a decreased one. At the bottom, catalytic sources can be characterized as a special kind of surrounding medium effect. The materials involving in catalysis may range from inorganic components as in zeolites, homogenous components, enzymes, catalytic antibodies, and ceramic materials. . With the enormous progress achieved by computing technology, an increasing number of models and phenomenological approaches are being used to describe the effects of a given surrounding medium on the electronic properties of selected subsystem. A number of quantum chemical methods and programs, currently applied to calculate in vacuum systems, have been supplemented with a variety of model representations. With the increasing number of methodologies applied to this important field, it is becoming more and more difficult for non-specialist to cope with theoretical developments and extended applications. For this and other reasons, it is was deemed timely to produce a book where methodology and applications were analyzed and reviewed by leading experts in the field.

Solvent Effects in Chemistry: Advances in Applications and Research

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Release : 2020-08-26
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Book Rating : 262/5 ( reviews)

Solvent Effects in Chemistry: Advances in Applications and Research - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Solvent Effects in Chemistry: Advances in Applications and Research write by Valérie Mireault. This book was released on 2020-08-26. Solvent Effects in Chemistry: Advances in Applications and Research available in PDF, EPUB and Kindle. In Solvent Effects in Chemistry: Advances in Applications and Research, a critical review of solvent influence on the performance of metal catalysts in the hydrogenation of carbonyl compounds, specifically unsaturated aldehydes, ketones and ketoesters, is provided.Additionally, the effects of solvent on the kinetics and mechanism of different reactions, stability, and sensitivity of the nanostructures are investigated.The uses of a large of variety of solvents varying from non-polar low basic solvents to polar strong basic solvents are discussed, showing that the properties of different solvents strongly influence the product composition of both studied reactions.The effects of solvent on the isomerization of monoterpenes epoxides as α- and β-pinene epoxide, limonene epoxide, verbenol epoxide, and nopol epoxide are explained from molecular and mechanistic points of view.The concluding study explores how heterolytic bond dissociation forms ionic species, while the corresponding homolytic bond dissociation results in the formation of neutral radical species.