Synthesis and Characterization of Porous Metal Phosphonates - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Synthesis and Characterization of Porous Metal Phosphonates write by Tiffany L. Kinnibrugh. This book was released on 2013. Synthesis and Characterization of Porous Metal Phosphonates available in PDF, EPUB and Kindle. This dissertation focuses on the challenge of developing porous metal arylphosphonates with both high crystallinity and functional porosity by using different synthetic approaches. Metal phosphonates are an extensive class of materials based upon extended inorganic-organic architectures such as chains, layers and three-dimensional networks. Metal phosphonates generally favor extended inorganic architectures leading to pillared materials with no porosity. We found that the use of template molecules, type of ligand and choice of metal ions could be used to deviate from the pillared structure. Many of these structures had interesting properties that were explored. The results can be divided into three areas: We developed non-pillared monovalent metal phosphonates by investigating both the role of water and template molecules in the solvothermal synthesis. The role of water in solvothermal reactions was found to have a profound influence on the structure of monovalent metal phosphonates and the structures could be tailored from zero/one-dimensional to two-dimensional. Non-pillared structures could be synthesized by using template molecules. For a zinc phosphonate, we converted a layered structure into a three-dimensional framework by using small template molecules in the solvothermal reaction. The compound exhibited reversible dehydration behavior. The change in the framework structure and guest positions was monitored during this process. Two different ligands were used in the development of porous aluminum phosphonates. One series exhibited reversible dehydration behavior, which had a dramatic influence on permanent porosity of the material. The stability of the dehydrated phase is a result of the geometry of the aluminum atom, which in some cases has coordinatively unsaturated metal sites. The second series was developed with ion exchange applications in mind therefore the pore environment was tailored to favor ion exchange processes. The most important aspect is that these compounds exhibit high selectivity for Th4+ ions. In total 28 new compounds were prepared, and their utility and structures clarified. The electronic version of this dissertation is accessible from http://hdl.handle.net/1969.1/151103
Metal Phosphonate Chemistry
Metal Phosphonate Chemistry - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Metal Phosphonate Chemistry write by Abraham Clearfield. This book was released on 2012. Metal Phosphonate Chemistry available in PDF, EPUB and Kindle. Metal phosphonate chemistry is a highly interdisciplinary field, as it encompasses several other areas, such as materials chemistry, gas storage, pharmaceutics, corrosion control, classical chemical synthesis, X-ray crystallography, powder diffraction, etc. It has also acquired additional significance due to "Metal-Organic Frameworks", as evidenced by the hundreds of papers published each year. This book fills the gap in the literature by summarising, in a concise way, the latest developments in the field. Metal phosphonate chemistry has seen impressive growth in the last 15-20 years and there is a clear need to systematize and organize all this growth. This unique book accomplishes just that need - edited by two experts, it includes contributions from other experienced researchers and organises, categorises and presents in an attractive way the latest hot topics in metal phosphonate chemistry and related applications. With an extensive bibliography, it is a great reference for academic and industrial researchers as well as students working in the field and will act as a starting point for further exploration of the literature. It is also of great interest to scientists working in the broader area of metal-organic frameworks and their applications.
Synthesis and Characterization of Porous Zinc Carboxyethylphosphonates
Synthesis and Characterization of Porous Zinc Carboxyethylphosphonates - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Synthesis and Characterization of Porous Zinc Carboxyethylphosphonates write by Chao Zhao. This book was released on 2012. Synthesis and Characterization of Porous Zinc Carboxyethylphosphonates available in PDF, EPUB and Kindle.
Metal Phosphonates and Phosphinates
Metal Phosphonates and Phosphinates - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Metal Phosphonates and Phosphinates write by Marco Taddei. This book was released on 2020-01-15. Metal Phosphonates and Phosphinates available in PDF, EPUB and Kindle. The present Special Issue of Symmetry is devoted to two important areas of global Riemannian geometry, namely submanifold theory and the geometry of Lie groups and homogeneous spaces. Submanifold theory originated from the classical geometry of curves and surfaces. Homogeneous spaces are manifolds that admit a transitive Lie group action, historically related to F. Klein's Erlangen Program and S. Lie's idea to use continuous symmetries in studying differential equations. In this Special Issue, we provide a collection of papers that not only reflect some of the latest advancements in both areas, but also highlight relations between them and the use of common techniques. Applications to other areas of mathematics are also considered.
Synthesis of Porous Metal Phosphonate Frameworks for Applications in Gas Separation and Storage
Synthesis of Porous Metal Phosphonate Frameworks for Applications in Gas Separation and Storage - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Synthesis of Porous Metal Phosphonate Frameworks for Applications in Gas Separation and Storage write by Michael Thomas Wharmby. This book was released on 2012. Synthesis of Porous Metal Phosphonate Frameworks for Applications in Gas Separation and Storage available in PDF, EPUB and Kindle.
