Synthesis and Reactivity of Early Transition Metal Complexes Containing Multiple Metal to Carbon, Nitrogen, Or Oxygen Bonds - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Synthesis and Reactivity of Early Transition Metal Complexes Containing Multiple Metal to Carbon, Nitrogen, Or Oxygen Bonds write by Scott M. Rocklage. This book was released on 1982. Synthesis and Reactivity of Early Transition Metal Complexes Containing Multiple Metal to Carbon, Nitrogen, Or Oxygen Bonds available in PDF, EPUB and Kindle.
Synthesis and Reactivity of Compounds Containing Ruthenium-carbon, -nitrogen, and -oxygen Bonds
Synthesis and Reactivity of Compounds Containing Ruthenium-carbon, -nitrogen, and -oxygen Bonds - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Synthesis and Reactivity of Compounds Containing Ruthenium-carbon, -nitrogen, and -oxygen Bonds write by . This book was released on 1990. Synthesis and Reactivity of Compounds Containing Ruthenium-carbon, -nitrogen, and -oxygen Bonds available in PDF, EPUB and Kindle. The products and mechanisms of the thermal reactions of several complexes of the general structure (PMe3)4Ru(X)(Y) and (DMPM)2Ru(X)(Y) where X and Y are hydride, aryl, and benzyl groups, have been investigated. The mechanism of decomposition depends critically on the structure of the complex and the medium in which the thermolysis is carried out. The alkyl hydride complexes are do not react with alkane solvent, but undergo C-H activation processes with aromatic solvents by several different mechanisms. Thermolysis of (PMe3)4Ru(Ph)(Me) or (PMe3)4Ru(Ph)2 leads to the ruthenium benzyne complex (PMe3)4Ru([eta]2-C6H4) (1) by a mechanism which involves reversible dissociation of phosphine. In many ways its chemistry is analogous to that of early rather than late organo transition metal complexes. The synthesis, structure, variable temperature NMR spectroscopy and reactivity of ruthenium complexes containing aryloxide or arylamide ligands are reported. These complexes undergo cleavage of a P-C bond in coordinated trimethylphosphine, insertion of CO and CO2 and hydrogenolysis. Mechanistic studies on these reactions are described. The generation of a series of reactive ruthenium complexes of the general formula (PMe3)4Ru(R)(enolate) is reported. Most of these enolates have been shown to bind to the ruthenium center through the oxygen atom. Two of the enolate complexes 8 and 9 exist in equilibrium between the O- and C-bound forms. The reactions of these compounds are reported, including reactions to form oxygen-containing metallacycles. The structure and reactivity of these ruthenium metallacycles is reported, including their thermal chemistry and reactivity toward protic acids, electrophiles, carbon monoxide, hydrogen and trimethylsilane. 243 refs., 10 tabs.
Transition Metal-Dinitrogen Complexes
Transition Metal-Dinitrogen Complexes - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Transition Metal-Dinitrogen Complexes write by Yoshiaki Nishibayashi. This book was released on 2019-05-06. Transition Metal-Dinitrogen Complexes available in PDF, EPUB and Kindle. A comprehensive book that explores nitrogen fixation by using transition metal-dinitrogen complexes Nitrogen fixation is one of the most prominent fields of research in chemistry. This book puts the focus on the development of catalytic ammonia formation from nitrogen gas under ambient reaction conditions that has been recently repowered by some research groups. With contributions from noted experts in the field, Transition Metal-Dinitrogen Complexes offers an important guide and comprehensive resource to the most recent research and developments on the topic of nitrogen fixation by using transition metal-dinitrogen. The book is filled with the information needed to understand the synthesis of transition metal-dinitrogen complexes and their reactivity. This important book: -Offers a resource for understanding nitrogen fixation chemistry that is essential for explosives, pharmaceuticals, dyes, and all forms of life -Includes the information needed for anyone interested in the field of nitrogen fixation by using transition metal-dinitrogen complexes -Contains state-of-the-art research on synthesis of transition metal-dinitrogen complexes and their reactivity in nitrogen fixation -Incorporates contributions from well-known specialists and experts with an editor who is an innovator in the field of dinitrogen chemistry Written for chemists and scientists with an interest in nitrogen fixation, Transition Metal-Dinitrogen Complexes is a must-have resource to the burgeoning field of nitrogen fixation by using transition metal-dinitrogen complexes.
Synthesis of Late Transition Metal Complexes Containing Metal-carbon Multiple Bonds
Synthesis of Late Transition Metal Complexes Containing Metal-carbon Multiple Bonds - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Synthesis of Late Transition Metal Complexes Containing Metal-carbon Multiple Bonds write by Tze Chung Lam. This book was released on 2019. Synthesis of Late Transition Metal Complexes Containing Metal-carbon Multiple Bonds available in PDF, EPUB and Kindle.
Cleavage of Carbon-Carbon Single Bonds by Transition Metals
Cleavage of Carbon-Carbon Single Bonds by Transition Metals - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Cleavage of Carbon-Carbon Single Bonds by Transition Metals write by Masahiro Murakami. This book was released on 2015-12-21. Cleavage of Carbon-Carbon Single Bonds by Transition Metals available in PDF, EPUB and Kindle. Edited by leading experts and pioneers in the field, this is the first up-to-date book on this hot topic. The authors provide synthetic chemists with different methods to activate carbon-carbon sigma bonds in organic molecules promoted by transition metal complexes. They explain the basic principles and strategies for carbon-carbon bond cleavage and highlight recently developed synthetic protocols based on this methodology. In so doing, they cover cleavage of C-C bonds in strained molecules, reactions involving elimination of carbon dioxide and ketones, reactions via retroallylation, and cleavage of C-C bonds of ketones and nitriles. The result is an excellent information source for researchers in academia and industry working in the field of synthetic organic chemistry, while equally serving as supplementary reading for advanced courses in organometallic chemistry and catalysis.
