The coordination chemistry of dithione ligands - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook The coordination chemistry of dithione ligands write by Benjamin Mogesa. This book was released on 2014. The coordination chemistry of dithione ligands available in PDF, EPUB and Kindle.
Variety in Coordination Modes of Ligands in Metal Complexes
Variety in Coordination Modes of Ligands in Metal Complexes - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Variety in Coordination Modes of Ligands in Metal Complexes write by Shinichi Kawaguchi. This book was released on 2012-12-06. Variety in Coordination Modes of Ligands in Metal Complexes available in PDF, EPUB and Kindle. Metal complexes play important roles as catalysts or other participants in synthetic and biological reactions. Substrates and sometimes attacking reagents also are activated through coordination with metal atoms or ions. In these events the natures not only of the central metals but also of ancillary ligands exert important influences on the stability and reactivity of the coordinated substrates. A ligand in general can adopt various coordination modes depending on its chemical environment, thus functioning as a probe. The number of coordination modes increases with increasing complexity of the ligand. In this book it is shown that even the simplest mono- and diatomic ligands such as H, CO, and N2 exhibit a variety of coordination modes, which are related to their reactions. The thiocyanate anion is taken up as a representative of the triatomic ambidentate ligands, and factors influencing the preferences for N- und S-bonding are summarized. Coordination chemistry of ß-dicarbonyl compounds is a highlight of this book. Acetylacetone, one of the most familiar Werner ligands, is shown to favor -carbon and n-allylic bonding in many instances. Its versatile behaviour in changing coordination modes is revealed.
Reactions of Coordinated Ligands
Reactions of Coordinated Ligands - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Reactions of Coordinated Ligands write by P.S. Braterman. This book was released on 2012-12-06. Reactions of Coordinated Ligands available in PDF, EPUB and Kindle. This, the second and final volume of Reactions of Coordinated Ligands, describes the chemistry of ligands bound through non-carbon atoms, and of coordinated carbon dioxide. As before, emphasis is on the underlying mechanisms, which provide a unity of understanding for superficially disparate processes. The wide range of topics covered illustrates well both the versatility and the usefulness of coordination chemistry in the controlled activation of ligands. Looking to the future, carbon dioxide is the feedstock of last resort. The homogeneous reduction of dinitrogen to ammonia now seems unlikely to replace the Haber process, but solution reactions also lead to more complex, varied, and valuable products. Nitrogen monoxide, a "non innocent" ligand, impinges as pollutant and reagent. Its rich chemistry stems from its linked roles as three-electron donor, and as extremely powerful -acceptor. In the hydrolysis and condensation of complexed amides, esters etc. , metals act both as templates and as tunable and poly functional Lewis acids. Here the control of hydrophobic and steric interactions begins to model the subtle mechanisms of biological specificity. Finally, phosphorus and sulfur are imporant both as ligand atoms in themselves, and as anchors for other functionalities. I would like to thank all those who have been involved in the writing and production of this work, and also my colleagues old and new, at Glasgow and the University of North Texas, for their support. Paul S. Braterman v CONTENTS 1. Reactions of Coordinated Carbon Dioxide 1 J. D. Miller 1.
Synthetic Coordination and Organometallic Chemistry
Synthetic Coordination and Organometallic Chemistry - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Synthetic Coordination and Organometallic Chemistry write by Alexander D. Garnovskii. This book was released on 2003-04-25. Synthetic Coordination and Organometallic Chemistry available in PDF, EPUB and Kindle. This reference describes standard and nonstandard coordination modes of ligands in complexes, the intricacies of polyhedron-programmed and regioselective synthesis, and the controlled creation of coordination compounds such as molecular and hn-p-complexes, chelates, and homo- and hetero-nuclear compounds. It offers a clear and concise review of modern synthetic techniques of metal complexes as well as lesser known gas- and solid-phase synthesis, electrosynthesis, and microwave and ultrasonic treatment of the reaction system. The authors pay special attention to o-hydroxyazomethines and their S-, Se-containing analogues, b-diketones, and quinines, among others, and examine the immediate interaction of ligands and metal salts or carbonyls.
Comprehensive Coordination Chemistry: the Synthesis Reactions Properties and Applications of Coordination Compounds
Comprehensive Coordination Chemistry: the Synthesis Reactions Properties and Applications of Coordination Compounds - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Comprehensive Coordination Chemistry: the Synthesis Reactions Properties and Applications of Coordination Compounds write by . This book was released on 1987. Comprehensive Coordination Chemistry: the Synthesis Reactions Properties and Applications of Coordination Compounds available in PDF, EPUB and Kindle.
