The Use of Sterically Encumbered Terphenyl and [beta]-diketiminate Ligands to Synthesize Low Coordinate, Multiply Bonded, and Hydride Derivatives of Heavier Group 13 and 15 Elements - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook The Use of Sterically Encumbered Terphenyl and [beta]-diketiminate Ligands to Synthesize Low Coordinate, Multiply Bonded, and Hydride Derivatives of Heavier Group 13 and 15 Elements write by Ned J. Hardman. This book was released on 2002. The Use of Sterically Encumbered Terphenyl and [beta]-diketiminate Ligands to Synthesize Low Coordinate, Multiply Bonded, and Hydride Derivatives of Heavier Group 13 and 15 Elements available in PDF, EPUB and Kindle.
Organometallic Compounds of Boron
Organometallic Compounds of Boron - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Organometallic Compounds of Boron write by K. Smith. This book was released on 1985. Organometallic Compounds of Boron available in PDF, EPUB and Kindle.
The Group 13 Metals Aluminium, Gallium, Indium and Thallium
The Group 13 Metals Aluminium, Gallium, Indium and Thallium - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook The Group 13 Metals Aluminium, Gallium, Indium and Thallium write by Simon Aldridge. This book was released on 2011-04-11. The Group 13 Metals Aluminium, Gallium, Indium and Thallium available in PDF, EPUB and Kindle. The last two decades have seen a renaissance in interest in the chemistry of the main group elements. In particular research on the metals of group 13 (aluminium, gallium, indium and thallium) has led to the synthesis and isolation of some very novel and unusual molecules, with implications for organometallic synthesis, new materials development, and with biological, medical and, environmental relevance. The Group 13 Metals Aluminium, Gallium, Indium and Thallium aims to cover new facts, developments and applications in the context of more general patterns of physical and chemical behaviour. Particular attention is paid to the main growth areas, including the chemistry of lower formal oxidation states, cluster chemistry, the investigation of solid oxides and hydroxides, advances in the formation of III-V and related compounds, the biological significance of Group 13 metal complexes, and the growing importance of the metals and their compounds in the mediation of organic reactions. Chapters cover: general features of the group 13 elements group 13 metals in the +3 oxidation state: simple inorganic compounds formal oxidation state +3: organometallic chemistry formal oxidation state +2: metal-metal bonded vs. mononuclear derivatives group 13 metals in the +1 oxidation state mixed or intermediate valence group 13 metal compounds aluminium and gallium clusters: metalloid clusters and their relation to the bulk phases, to naked clusters, and to nanoscaled materials simple and mixed metal oxides and hydroxides: solids with extended structures of different dimensionalities and porosities coordination and solution chemistry of the metals: biological, medical and, environmental relevance III-V and related semiconductor materials group 13 metal-mediated organic reactions The Group 13 Metals Aluminium, Gallium, Indium and Thallium provides a detailed, wide-ranging, and up-to-date review of the chemistry of this important group of metals. It will find a place on the bookshelves of practitioners, researchers and students working in inorganic, organometallic, and materials chemistry.
On the Catalytic Efficacy of Low-Oxidation State Group 14 Complexes
On the Catalytic Efficacy of Low-Oxidation State Group 14 Complexes - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook On the Catalytic Efficacy of Low-Oxidation State Group 14 Complexes write by Terrance John Hadlington. This book was released on 2017-02-14. On the Catalytic Efficacy of Low-Oxidation State Group 14 Complexes available in PDF, EPUB and Kindle. This outstanding thesis describes a detailed investigation into the use of low-oxidation-state group 14 complexes in catalysis, developed at the cutting edge of inorganic and organometallic chemistry. It includes the preparation of a number of landmark compounds, some of which challenge our current understanding of metal–metal bonding and low-oxidation-state main group chemistry. Among the many highlights of this thesis, the standout result is the development of the first well-defined, low- oxidation-state main group hydride systems as highly efficient catalysts in the hydroboration of carbonyl substrates, including carbon dioxide, which are as efficient as those observed in more traditional, transition-metal catalyses. These results essentially define a new subdiscipline of chemistry.
Organometallic Compounds of Low-Coordinate Si, Ge, Sn and Pb
Organometallic Compounds of Low-Coordinate Si, Ge, Sn and Pb - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Organometallic Compounds of Low-Coordinate Si, Ge, Sn and Pb write by Vladimir Ya. Lee. This book was released on 2011-07-22. Organometallic Compounds of Low-Coordinate Si, Ge, Sn and Pb available in PDF, EPUB and Kindle. Until recently the low-coordinate compounds of the heavier elements of group 14 were known only as transient, unstable species which were difficult to isolate. However recent developments have led to the stabilisation of these compounds and today heavier group 14 element cations, radicals, anions, carbene analogues, alkene and alkyne analogues and aromatics have all been prepared as highly reactive, stable, fully characterizable and readily available organometallic reagents. Organometallic Compounds of Low-Coordinate Si, Ge, Sn and Pb describes the chemistry of this exciting new class of organometallics, with an emphasis on their major similarities and differences with the analogous species in organic chemistry. Topics covered include include the synthesis, structure, reactions and synthetic applications of : Si-, Ge-, Sn and Pb-centered cations, radicals and anions heavy analogues of carbenes: silylenes, germylenes, stannylenes and plumbylenes heavy analogues of alkenes: disilenes, digermenes, distannenes, diplumbenes heavy analogues of alkynes: disilynes, digermynes, distannynes, diplumbynes, and their valence isomers heteronuclear derivatives: silenes, germenes, stannenes, silagermenes, silastannenes, germastannenes heavy analogues of alkenes of the type: >E14=E13-, >E14=E15-, >E14=E16 [where E13, E14, E15 and E16 are elements of the groups 13, 14, 15 and 16] cyclic compounds (three-, four-, five-, and six-membered rings) heavy analogues of 1,3-dienes, allenes and other cumulenes heavy analogues of aromatic compounds; including a comparison between organometallic and organic aromaticity Organometallic Compounds of Low-Coordinate Si, Ge, Sn and Pb is an essential guide to this emerging class of organometallic reagents for researchers and students in main group, organometallic, synthetic and silicon chemistry
