Transition Metal Catalyzed Transformations for Synthesis of Complex Organic Molecules - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Transition Metal Catalyzed Transformations for Synthesis of Complex Organic Molecules write by . This book was released on 2015. Transition Metal Catalyzed Transformations for Synthesis of Complex Organic Molecules available in PDF, EPUB and Kindle.
Transition Metals in the Synthesis of Complex Organic Molecules
Transition Metals in the Synthesis of Complex Organic Molecules - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Transition Metals in the Synthesis of Complex Organic Molecules write by Louis S. Hegedus. This book was released on 1999. Transition Metals in the Synthesis of Complex Organic Molecules available in PDF, EPUB and Kindle. This second edition offers easy access to the field of organotransition metal chemistry. The book covers the basics of transition metal chemistry, giving a practical introduction to organotransition reaction mechanisms.
Transition Metal-Catalyzed Carbene Transformations
Transition Metal-Catalyzed Carbene Transformations - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Transition Metal-Catalyzed Carbene Transformations write by Jianbo Wang. This book was released on 2022-05-16. Transition Metal-Catalyzed Carbene Transformations available in PDF, EPUB and Kindle. Presents an up-to-date overview of the rapidly growing field of carbene transformations Carbene transformations have had an enormous impact on catalysis and organometallic chemistry. With the growth of transition metal-catalyzed carbene transformations in recent decades, carbene transformations are today an important compound class in organic synthesis as well as in the pharmaceutical and agrochemical industries. Edited by leading experts in the field, Transition Metal-Catalyzed Carbene Transformations is a thorough summary of the most recent advances in the rapidly expanding research area. This authoritative volume covers different reaction types such as ring forming reactions and rearrangement reactions, details their conditions and properties, and provides readers with accurate information on a wide range of carbene reactions. Twelve in-depth chapters address topics including carbene C-H bond insertion in alkane functionalization, the application of engineered enzymes in asymmetric carbene transfer, progress in transition-metal-catalyzed cross-coupling using carbene precursors, and more. Throughout the text, the authors highlight novel catalytic systems, transformations, and applications of transition-metal-catalyzed carbene transfer. Highlights the dynamic nature of the field of transition-metal-catalyzed carbene transformations Summarizes the catalytic radical approach for selective carbene cyclopropanation, high enantioselectivity in X-H insertions, and bio-inspired carbene transformations Introduces chiral N,N'-dioxide and chiral guanidine-based catalysts and different transformations with gold catalysis Discusses approaches in cycloaddition reactions with metal carbenes and polymerization with carbene transformations Outlines multicomponent reactions through gem-difunctionalization and transition-metal-catalyzed cross-coupling using carbene precursors Transition Metal-Catalyzed Carbene Transformations is essential reading for all chemists involved in organometallics, including organic and inorganic chemists, catalytic chemists, and chemists working in industry.
New Pathways for Organic Synthesis
New Pathways for Organic Synthesis - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook New Pathways for Organic Synthesis write by H.M. Colquhoun. This book was released on 2012-12-06. New Pathways for Organic Synthesis available in PDF, EPUB and Kindle. The continually growing contribution of transition metal chemistry to synthetic organic chemistry is, of course, widely recognized. Equally well known is the difficulty in keeping up-to-date with the multifarious reactions and procedures that seem to be spawned at an ever-increasing rate. These can certainly be summarized on the basis of reviews under the headings of the individual transition metals. More useful to the bench organic chemist, however, would be the opposite type of concordance based on the structural type of the desired synthetic product. This is the approach taken in the present monograph, which presents for each structural entity a conspectus of the transition metal-mediated processes that can be employed in its production. The resulting comparative survey should be a great help in devising the optimum synthetic approach for a particular goal. It is presented from an essentially practical viewpoint, with detailed direc tions interspersed in the Houben-Weyl style. The wide scope of the volume should certainly encourage synthetic organic chemists to utilize fully the range and versatility of these transition metal-mediated processes. This will certainly be a well-thumbed reference book! R. A. RAPHAEL Cambridge University v Preface In recent years an enormous amount of work has been done on the catalysis of organic reactions by various transition metal species and on the organic reactivity of organo-transition-metal compounds.
Transition-metal-catalyzed Reactions
Transition-metal-catalyzed Reactions - read free eBook in online reader or directly download on the web page. Select files or add your book in reader. Download and read online ebook Transition-metal-catalyzed Reactions write by Astrid Marisol Parsons. This book was released on 2019. Transition-metal-catalyzed Reactions available in PDF, EPUB and Kindle. "Transition-metal-catalyzed reactions have revolutionized the field of organic chemistry, enabling for the efficient synthesis of biologically and pharmaceutically relevant molecules. To this extent, this dissertation will focus on the development of new catalytic methods for the synthesis of organic molecules. Chapter 2 reports on the multimetallic Ni- and Pd- cross-electrophile coupling of vinyl bromides with vinyl triflates to form highly substituted 1,3-dienes. These dienes were subjected to Diels-Alder reactions and mechanistic experiments were performed to elucidate the reaction mechanism. Chapter 3 discusses the [Co(TPP)]-catalyzed (TPP = tetraphenylporphyrin) formation of substituted piperidines. Optimization studies, substrate screening, and mechanistic investigations will be discussed. Chapter 4 elaborates on how substitution on a variety of simple ketones and esters affects selectivity for C-H bond activation by tris-(3,5-dimethylpyrazolyl)borate rhodium complex. Lastly, Chapter 5 discusses the synthesis of novel bis((4,5-dihydrooxazol-2-yl)methyl)amine (ambox) ligated cobalt complexes. Importantly, this work provides the first insight into functionalization reactions of ambox-ligated cobalt complexes. Furthermore, these complexes are active towards hydrosilylation, hydroboration, C-C bond formation, and hydrogenation reactions alluding to the potential of this new class of cobalt-complexes for homogenous catalysis"--Page x.
